UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 1 (11)
1. COMPANY AND PRODUCT INFORMATION 1.1 Identification of the substance/preparation
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak®
Use of the substance/preparation 1.3 Company/undertaking identification Importer Manufacturer
Fax: +440 960-5668 Internet: www.brushwellman.com
1.4 Emergency Phone No. 2. HAZARDS IDENTIFICATION
2.1 Classification and labelling of preparation
Metallic product which poses little or no immediate hazard in solid form. See label in Section 16. If the material is involved in a fire; pressure-demand self-contained breathing apparatus and protective clothing must be worn by persons potentially exposed to the airborne particulate during or after a fire.
2.2 Dangerous properties of dust/fumes/mist
Processes which generate particulates from the working of alloys can cause hazards to health or environmental effects. May cause an allergic reaction on contact with skin or by inhalation.
3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Components, classification and concentration Substance EINICS-Nr. Symbol Hazard Index-Nr. Symbol R-phrases* statements (CLP) UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 2 (11)
*For complete wording of R-phrases and hazard statements see section 16.
Substance(weight %) Moldmax®HH/LH Weldpak®
4. FIRST-AID MEASURES General Information Show this safety data sheet to the doctor on duty. Inhalation
If dust, fumes or mist inhaled, remove patient to fresh air, allow to rest and keep warm. Breathing difficulty caused by inhalation of particulate requires immediate removal to fresh air. If breathing has stopped, perform artificial respiration and obtain medical help
Beryllium: The beryllium in this product is not known to cause acute health effects. Inhaling particulate containing beryllium may cause a serious, chronic lung disease called Chronic Beryllium Disease (CBD) in some individuals. Cobalt: May cause asthmatic attacks due to allergic sensitization of the respiratory tract. May cause asthma and shortness of breath. Copper: Inhalation of particulate containing metallic copper can cause ulceration and perforation of the nasal septum.
Skin contact Thoroughly wash skin cuts or wounds to remove all particulate debris from the wound. Seek medical attention for wounds that cannot be thoroughly cleansed. Treat skin cuts and wounds with standard first aid practices such as cleansing, disinfecting and covering to prevent wound infection and contamination before continuing work. Obtain medical help for persistent irritation. Material accidentally implanted or lodged under the skin must be removed. Beryllium: Particulate that becomes lodged under the skin has the potential to induce sensitization and skin lesions. Cobalt: Prolonged and/or repeated contact may cause dermatitis. Copper: Particulate may cause a greenish-black skin discoloration. Eye contact Avoid getting finely divided particles in the eyes. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Copper: Particulate in the eyes may cause discoloration. Ingestion Alloys in massive form are not hazardous, but should be kept out of the mouth. Finely divided particles may be easily ingested along with food, drink or smoking. If large quantities ingested, seek medical advice. Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 3 (11)
Beryllium: The health effect of ingestion of beryllium in the form found in this product is unknown. Cobalt: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause allergic reaction. Copper: Copper ingestion causes nausea, vomiting, abdominal pain, metallic taste, and diarrhea. Ingestion of large doses may cause stomach and intestine ulceration, jaundice, and kidney and liver damage.
Chronic (long-term health effects) Beryllium: Inhaling particulate containing beryllium may cause a serious, chronic lung disease called chronic beryllium disease (CBD) in some individuals. Over time, lung disease can be fatal. Chronic beryllium disease is a hypersensitivity or allergic condition in which the tissues of the lungs become inflamed. This inflammation, sometimes with accompanying fibrosis (scarring), may restrict the exchange of oxygen between the lungs and the bloodstream. Medical science suggests that CBD may be related to genetic factors. Cobalt: Repeated exposure may cause allergic respiratory reaction (asthma). Chronic inhalation of particulate may lead to restricted pulmonary function and lung fibrosis (scarring). Chronic ingestion may result in heart damage and/or failure, vomiting, convulsions and thyroid enlargement. Repeated exposure may cause sensitization dermatitis. Copper: Prolonged or repeated exposure to copper can discolor skin and hair and irritate the skin; may cause mild dermatitis, runny nose, and irritation of the mucous membranes. Repeated ingestion may damage the liver and kidneys. Repeated Inhalation can cause chronic respiratory disease. Carcinogenic References Beryllium: The International Agency for Research on Cancer (IARC) lists beryllium as a Group 1 – Known Human Carcinogen. The National Toxicology Program (NTP) lists beryllium as known to be human carcinogens. IARC lists beryllium as a known human carcinogen (Group 1) and notes that the work environment of workers involved in refining, machining and producing beryllium metal was associated with an increased risk of lung cancer, “the greater excess was in workers hired before 1950 when exposures to beryllium in the work place were relatively uncontrolled and much higher than in subsequent decades”; and “the highest risk for lung cancer being observed among individuals diagnosed with acute beryllium-induced pneumonitis, who represent a group that had the most intense exposure to beryllium.” IARC further noted that “Prior to 1950, exposure to beryllium in working environments was usually very high, and concentrations exceeding 1 mg/m3 [1000 micrograms per cubic meter] were not unusual.” Cobalt: The International Agency for Research on Cancer (IARC) lists cobalt as a Group 2B – Possibly Carcinogenic to Humans. OSHA lists cobalt as a possible select carcinogen. Medical Conditions Aggravated by Exposure Persons with impaired pulmonary function, airway diseases, or conditions such as asthma, emphysema, chronic bronchitis, etc. may incur further impairment if particulate is inhaled. If prior damage or disease to the neurologic (nervous), circulatory, hematologic (blood), or urinary (kidney) systems has occurred, proper screening or examinations should be conducted on individuals who may be exposed to further risk where handling and use of this material may cause exposure. Beryllium: The effects of chronic beryllium disease on the lungs and heart are additive to the effects of other health conditions. Copper: Persons with pre-existing skin disorders or impaired liver, kidney, or pulmonary function or pre-existing Wilson's disease may be more susceptible to the effects of this material. UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 4 (11) Treatment of Chronic Beryllium Disease There is no known treatment which will cure chronic beryllium disease. Prednisone or other corticosteroids are the most specific treatment currently available. They are directed at suppressing the immunological reaction and can be effective in diminishing signs and symptoms of chronic beryllium disease. In cases where steroid therapy has had only partial or minimal effectiveness, other immunosuppressive agents, such as cyclophosphamide, cyclosporine, or methotrexate, have been used. These latter agents remain investigational. Further, in view of the potential side effects of all the immunosuppressive medications, including steroids such as prednisone, they should be used only under the direct care of a physician. In general, these medications should be reserved for cases with significant symptoms and/or significant loss of lung function. Other symptomatic treatment, such as oxygen, inhaled steroids or bronchodilators, may be prescribed by some physicians and can be effective in selected cases. The decision about when and with what medication to treat is a judgment situation for individual physicians. For the most part, treatment is reserved for those persons with symptoms and measurable loss of lung function. The value of starting oral steroid treatment, before signs or symptoms are evident, remains a medically unresolved issue. The effects of continued low exposure to beryllium are unknown for individuals who are sensitized to beryllium or who have a diagnosis of chronic beryllium disease. It is generally recommended that persons who are sensitized to beryllium or who have CBD terminate their occupational exposure to beryllium. 5. FIRE-FIGHTING MEASURES
Non-combustible as a solid. No ignition as layer of sub 44 micron particles of copper.
Not applicable to solids. No ignition as cloud of sub 44 micron particles of nominal copper.
This material is non-combustible. Use extinguishing media appropriate to the surrounding fire.
Do not use water to extinguish fires around operations involving molten metal
due to the potential for steam explosions.
Pressure-demand self-contained breathing apparatus must be worn by
firefighters or any other persons potentially exposed to the metal fumes or dust released during or after a fire.
6. ACCIDENTAL RELEASE MEASURES
If this material is a particulate, establish a restricted entry zone based on the severity of the spill. Persons entering the restricted zone must wear adequate respiratory protection and protective clothing appropriate for the severity of the spill (see Section 8). Cleanup spills with a vacuum system utilizing a high efficiency particulate air (HEPA) filtration system followed by wet cleaning methods. Special precautions must be taken when changing filters on HEPA vacuum cleaners used to clean up hazardous materials. Be careful to minimize airborne generation of particulate and avoid contamination of air and water.
UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 5 (11)
7. HANDLING AND STORAGE Recommendations for safe handling No special precautions necessary for alloys in massive form other than normal physical handling techniques. Extraction should be used when working with particulate material (dust, fumes, mist). Avoid prolonged inhalation of dust. Wear gloves to avoid contact with skin (see Section 8). Storage Store in a dry area. 8.EXPOSURE CONTROLS/PERSONAL PROTECTION Constituents
*ALL CONCENTRATIONS ARE IN MILLIGRAMS PER CUBIC METER OF AIR (at the concentrations noted above, these constituents may not be visible to the human eye) A leading scientific body recommending occupational standards is the American Conference of Governmental Industrial Hygienists (ACGIH). The ACGIH recommends standards for all listed substances. The ACGIH defines a threshold limit value (standard) as follows: “Threshold Limit Values refer to airborne concentrations of substances and represent conditions under which it is believed that nearly all workers may be repeatedly exposed day after day without adverse health effects. Because of wide variation in individual susceptibility, however, a small percentage of workers may experience discomfort from some substances at concentrations at or below the threshold limit; a smaller percentage may be affected more seriously by aggravation of a pre-existing condition or by development of an occupational illness.” “Individuals may also be hypersusceptible or otherwise unusually responsive to some industrial chemicals because of genetic factors, age, personal habits (smoking, alcohol, or other drugs), medication, or previous exposures. Such workers may not be adequately protected from adverse health effects from certain chemicals at concentrations at or below the threshold limits.”
ACGIH = American Conference of Governmental Industrial Hygienists OSHA = Occupational Safety and Health Administration PEL = Eight-Hour Average Permissible Exposure Limit (OSHA) CEILING = Not To Be Exceeded Except for Peak Limit (OSHA) PEAK = 30-Minute Maximum Duration Concentration Above Ceiling Limit (OSHA) TLV = Eight-Hour Average Threshold Limit Value (ACGIH) TLV-STEL = 15-Minute Short Term Exposure Limit (ACGIH) CAS = Chemical Abstract Service NIOSH = National Institute for Occupational Safety and Health
RTECS = Registry of Toxic Effects of Chemical Substances The manufacture recommends following good industrial hygiene practice which includes reducing airborne exposures to the lowest feasible level for all constituents in this product.
Control of Exposure 8.2.1 Respiratory protection
Extraction should be used when working with particulate material (dust, fumes, mist). In case of prolonged or frequent exposure to particulates, wear particle filter mask. When airborne exposures exceed or have the potential to exceed the occupational limits shown in Section 8.1, approved respirators must be used as specified by an Industrial Hygienist or other
UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 6 (11)
qualified professional. Respirator users must be medically evaluated to determine if they are physically capable of wearing a respirator. Quantitative and/or qualitative fit testing and respirator training must be satisfactorily completed by all personnel prior to respirator use. Users of tight fitting respirators must be clean shaven on those areas of the face where the respirator seal contacts the face. Exposure to unknown concentrations of particulate requires the wearing of a pressure-demand airline respirator or pressure-demand self-contained breathing apparatus (SCBA). Use pressure-demand airline respirators when performing jobs with high potential exposures such as changing filters in a baghouse air cleaning device.
8.2.2 Skin protection
Wear hand protection, eg leather gloves when handling alloys with sharp edges to avoid cuts. Always wear disposable nitrile or vinyl gloves when handling particulate material to avoid skin contact. Where necessary wear the disposable gloves under work gloves to protect against both types of hazard.
8.2.3 Eye protection
Always wear eye protection when handling dusts and other particulates, eg safety glasses with side protection, safety goggles or visor. Wear safety glasses, goggles, face shield, or welder’s helmet when risk of eye injury is present, particularly during melting, casting, machining, grinding, welding, powder handling, etc.
8.2.4 Protective clothing
Always wear protective clothing when handling dusts and other particulates. Wear gloves to prevent contact with particulate or solutions. Wear gloves to prevent metal cuts and skin abrasions during handling.
8.2.5 Other protective equipment
Protective overgarments or work clothing must be worn by persons who may become contaminated with particulate during activities such as machining, furnace rebuilding, air cleaning equipment filter changes, maintenance, furnace tending, etc. Contaminated work clothing and overgarments must be managed in a controlled manner to prevent secondary exposure to workers of third parties, to prevent the spread of particulate to other areas, and to prevent particulate from being taken home by workers.
8.2.6 General hygiene measures
Wash hands well with soap and water after handling dusty materials. Wash contaminated clothing to avoid secondary contamination or contamination of other personnel.
8.3 Technical advice. 8.3.1 Ventilation and engineering controls
Whenever possible, the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne particulate. Where utilized, exhaust inlets to the ventilation system must be positioned as close as possible to the source of airborne generation. Avoid disruption of the airflow in the area of a local exhaust inlet by equipment such as a man-cooling fan. Check ventilation equipment regularly to ensure it is functioning properly. Provide training on the use and operation of ventilation to all users. Use qualified professionals to design and install ventilation systems.
8.3.2 Work practises
Develop work practices and procedures that prevent particulate from coming in contact with worker skin, hair, or personal clothing. If work practices and/or procedures are ineffective in controlling airborne exposure or visual particulate from deposition on skin, hair, or clothing, provide appropriate cleaning/washing facilities. Procedures should be written that clearly communicate the facility’s requirements for protective clothing and personal hygiene. These clothing and personal hygiene requirements help keep particulate from being spread to non-production areas or from being taken home by the worker. Never use compressed air to clean
UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 7 (11)
work clothing or other surfaces. Fabrication processes may leave a residue of particulate on the surface of parts, products or equipment that could result in employee exposure during subsequent material handling activities. As necessary, clean loose particulate from parts between processing steps. As a standard hygiene practice, wash hands before eating or smoking. To prevent exposure, remove surface scale or oxidation formed on cast or heat treated products in an adequately ventilated process prior to working the surface.
8.3.3 Wet methods
Machining operations are usually performed under a liquid lubricant/coolant flood which assists in reducing airborne particulate. However, the cycling through of machine coolant containing finely divided particulate in suspension can result in the concentration building to a point where the particulate may become airborne during use. Certain processes such as sanding and grinding may require complete hooded containment and local exhaust ventilation. Prevent coolant from splashing onto floor areas, external structures or operators’ clothing. Utilize a coolant filtering system to remove particulate from the coolant.
8.4 Housekeeping & maintenance
Use vacuum and wet cleaning methods for particulate removal from surfaces. Be certain to de-energize electrical systems, as necessary, before beginning wet cleaning. Use vacuum cleaners with high efficiency particulate air (HEPA). Do not use compressed air, brooms, or conventional vacuum cleaners to remove particulate from surfaces as this activity can result in elevated exposures to airborne particulate. Follow the manufacturer’s instructions when performing maintenance on HEPA filtered vacuums used to clean hazardous materials.During repair or maintenance activities the potential exists for exposures to particulate in excess of the occupational standards. Under these circumstances, protecting workers can require the use of specific work practices or procedures involving the combined use of ventilation, wet and vacuum cleaning methods, respiratory protection, decontamination, special protective clothing, and when necessary, restricted work zones.
8.5 Welding
In accordance with OSHA regulation 29 CFR 1910.252 welding of materials containing beryllium is regulated as follows: Welding or cutting indoors, outdoors, or in confined spaces involving beryllium containing base or filler metals shall be done using local exhaust ventilation and pressure-demand airline respirators unless atmospheric tests under the most adverse conditions have established that the workers’ exposure is within the acceptable concentrations defined by 29 CFR 1910.1000. In all cases, workers in the immediate vicinity of the welding or cutting operations shall be protected as necessary by local exhaust ventilation or airline respirators.
8.6 Exposure Characterization
Determine exposure to airborne particulate by air sampling in the employee breathing zone, work area, and department. Utilize an Industrial Hygienist or other qualified professional to specify the frequency and type of air sampling. Develop and utilize a sampling strategy which identifies the extent of exposure variation and provides statistical confidence in the results. Conduct an exposure risk assessment of processes to determine if conditions or situations exist which dictate the need for additional controls or improved work practices. Make air sample results available to employees. Beryllium: Medical surveillance for beryllium health effects includes (1) skin examination, (2) respiratory history, (3) examination of the lungs, (4) lung function tests (FVC and FEV1), and (5) periodic chest x-ray. In addition, a specialized, specific, immunological blood test, the beryllium blood lymphocyte proliferation test (BLPT), is available to assist in the diagnosis of beryllium related reactions. Individuals who have an abnormal BLPT are normally referred to a lung specialist for additional specific tests to determine if chronic beryllium disease is present. Note: Substantial inter- and intra-laboratory disagreement exists among the
UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 8 (11)
laboratories that conduct this test. The BLPT does not at this time meet the criteria for a screening test.
9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL PROPERTIES Product names Melting point
10. STABILITY AND REACTIVITY
10.1 Stability
Alloys are stable. Corrosion should not take place under normal circumstances. Hazardous decomposition products: none under normal conditions of use. Hazardous Polymerization will not occur.
10.2 Materials to avoid
Reacts with some acids and caustic solutions to produce hydrogen gas. Hydrogen gas can be an explosion hazard. Powdered aluminum and chlorinated hydrocarbons may react with explosive violence.
1. TOXICOLOGICAL INFORMATION 11.1 Effect on humans
Alloys contain cobalt which carries a risk of producing an allergic reaction following prolonged contact or in already sensitised persons. Particles from the alloy are not judged as acute toxic.
11.2 Acute toxicity
No LC50 or LD50 has been established for the mixture as a whole. Cobalt: Oral LD50 rat
11.3 Further information
For questions concerning toxicological information, write to: Medical Director, Brush Wellman Inc., 14710 West Portage River South Road, Elmore, Ohio 43416-9502.
12. ECOLOGICAL INFORMATION
12.1 Mobility
Metal alloys are not soluble in water. Particles formed by working alloys can be transported in the air.
12.2 Bioaccumulation
Alloys contain heavy metals which can probably bioaccumulate in the food chain.
12.3 Ecotoxicity
Alloys contain metals which are considered to be very toxic towards aquatic organisms. Finely divided alloys are therefore considered harmful to aquatic organisms.
12.4 Further information
In massive form alloys present no hazards to the aquatic environment. Particles and ions can, never the less, enter the aquatic compartment by means of dusts or smoke, or by liberation due to erosion thereby introducing iron or heavy metals into the ground or water. This material can be recycled; contact your Sales Representative.
UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 9 (11) 13. DISPOSAL CONSIDERATIONS
The unused product (massive alloy) is not classified as hazardous waste. Dispose in accordance with appropriate government regulations. When recycled (used in a process to recover metals), this material is not classified as hazardous waste under federal law. Seal particulate or particulate containing materials inside two plastic bags, place in a DOT approved container, and label appropriately. When spent products are declared solid wastes (no longer recyclable) and any residues of finely divided product (particles, dust, fumes) are regarded as Hazardous Waste and must be labeled, managed and disposed of, in accordance with federal, state and local requirements. Contact your local entrepreneur for advice.
14. TRANSPORT INFORMATION
There are no U.S. Department of Transportation hazardous material regulations which apply to the packaging and labeling of this product as shipped by Brush Wellman. Hazard Communication regulations of the U.S. Occupational Safety and Health Administration require this product be labelled in the U.S.A. See section 16.
15. REGULATORY INFORMATION 15.1 Environmental Protection Agency (EPA) AMBIENT AIR EMISSIONS: Most process air emission sources will require an air permit from a local and/or state air pollution control agency. The use of air cleaning equipment may be necessary to achieve the permissible emission. Tempered makeup air should be provided to prevent excessive negative pressure in a building. Direct recycling of cleaned process exhaust air is not recommended. Plant exhausts should be located so as not to re-enter the plant through makeup air or other inlets. Regular maintenance and inspection of air cleaning equipment and monitoring of operating parameters is recommended to ensure adequate efficiency is maintained. WASTEWATER: Wastewater regulations can vary considerably. Contact your local and state governments to determine their requirements. TOXIC SUBSTANCES CONTROL ACT: Component(s) of this material is/are listed on the TSCA Chemical Substance Inventory of Existing Chemical Substances SARA TITLE III REPORTING REQUIREMENTS: On February 16, 1988, the U.S. Environmental Protection Agency (EPA) issued a final rule that implements the requirements of the Superfund Amendments and Reauthorization Act (SARA) Title III, Section 313 (53) Federal Register 4525. Title III is the portion of SARA concerning emergency planning and community right-to-know issues. Section 313 covers annual emission reporting on specific chemicals which are manufactured, processed or used at certain U.S. Industrial facilities. Brush Wellman products are reportable under the Section 313 category of Compounds and/or Mixtures. These mixtures contain one or more of the following reportable constituents: Beryllium, Cobalt and Copper. The specific chemical makeup, concentration by weight and the Chemical Abstracts Services number for each of our products is provided in Section 3. You may obtain additional information by calling the EPA SARA Title III Hotline at 1-800-535-0202 or 703- 412-9810. UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 10 (11)
15.2 State regulations Beryllium is listed on the following state right-to-know lists: California, New Jersey, Florida, Pennsylvania, Minnesota and Massachusetts. The following statement is made in order to comply with the California State Drinking Water Act - Warning: This product contains BERYLLIUM, a chemical known to the state of California to cause cancer. California No Significant Risk Level: CAS# 7440-41-7: No significant risk level = 0.1 µg/day Cobalt is listed on the following state right-to-know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts. The following statement is made in order to comply with the California Safe Drinking Water Act WARNING: This product contains COBALT, a chemical known to the state of California to cause cancer. California No Significant Risk Level: Not listed. Copper is listed on the following state right–to-know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts. California, no Significant Risk Level: Not listed. CANADA Constituent DSL/NDSL Ingredient Classification Disclosure List
15.3 General Guidance
Classifications mentioned in Section 3 concerns substances in their crushed form.
16. OTHER INFORMATION
16.1 Full text of R-phrases used in Section 3
Irritating to eyes and respiratory system
R36/37/38 Irritating to eyes, respiratory system and skin R48/23
Toxic: danger of serious damage to health by prolonged exposure through inhalation
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
May cause long-term adverse effects in the aquatic environment
16.2 Full text of Hazard statements used in Section3
May cause allergy or asthma symptoms of breathing difficulties if inhaled
Causes damage to organs through prolonged or repeated exposure
Very toxic to aquatic life with long lasting effects
May cause long lasting harmful effects to aquatic life
16.1 Modifications since previous version UDDEHOLM TOOLING SAFETY DATA SHEET
(Prepared according to EU Directives 1907/2006 (REACH) & 1272/2008 (CLP))
UDDEHOLM TOOLING (BRUSH WELLMAN) Alloys: Moldmax®HH/LH and Weldpak® Issued: 01-06-01 Revised: 08-01-10 Page: 11 (11)
16.2 Sources of information Following is the label which accompanies this product during shipment. Moldmax®, Weldpak® INHALING DUST OR FUMES MAY CAUSE CHRONIC BERYLLIUM DISEASE, A SERIOUS CHRONIC LUNG DISEASE, IN SOME INDIVIDUALS. CANCER HAZARD. OVER TIME, LUNG DISEASE AND CANCER CAN BE FATAL. TARGET ORGAN IS PRIMARILY THE LUNG. READ THE MATERIAL SAFETY DATA SHEET (MSDS) ON FILE WITH YOUR EMPLOYER BEFORE WORKING WITH THIS MATERIAL.
This product contains beryllium and may contain nickel. Overexposure to beryllium by inhalation may cause chronic beryllium disease, a serious chronic lung disease.
If processing or recycling produces particulate, use exhaust ventilation or other controls designed to prevent exposure to workers. Examples of such activities include melting, welding, grinding, abrasive sawing, sanding and polishing. Any activity which abrades the surface of this material can generate airborne particulate. The Occupational Safety and Health Administration (OSHA) has set mandatory limits on occupational exposures. Copper beryllium, in solid form and as contained in finished products presents no special health risks. Sold for manufacturing purposes only. This product can be recycled; contact your sales representative. The Occupational Safety and Health Administration requires employers to provide training in the proper use of this product.
For further information, please telephone or write to: Product Stewardship Department, Brush Wellman Inc., 6070 Parkland Boulevard, Mayfield Heights, Ohio 44124, telephone: (800) 862-4118, www.brushwellman.com. For transportation emergency call Chemtrec at (800) 424-9300.
*Label color (light blue edge with black lettering)
16.3 References to further information IMPORTANT: If you have any questions or require additional information regarding the materials described in this Material Safety Data Sheet, please telephone or write to the Product Stewardship Department at the location given on page 1. Additional product safety information, such as Safety Facts, is available from your sales representative or at http://www.brushwellman.com/. Additional information and guidance on the safe use and handling of these materials is available in the “Interactive Guide to Working Safely with Beryllium and Beryllium-containing Materials.” This computer based tool can be accessed online at www.berylliumsafety.com. For any further information, please contact:
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