SAFETY DATA SHEET Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) METALLIC ZINC 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name Synonyms
: Zinc Metal Sheets; Zinc Metal Shot; Zinc Metal Strips
REACH Registration Chemical Formula 1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
: Alloys (low alloy steels, stainless steel, copper and brass, permanent magnets, electrical resistance
alloys); electroplated protective coatings; electroformed coatings; alkaline storage batteries, fuel cell
electrodes, catalyst for methanation of fuel gases and hydrogenation of vegetable oils; making of
Uses advised against 1.3 Details of the supplier of the safety data sheet Supplier Email address of person responsible for SDS 1.4 Emergency telephone number National advisory body/Poison Centre Telephone number : Please contact your national poison centre/advisory body. Supplier Telephone number : +264 63 271 2000 / +264 81 146 2610 (Emergency Coordinator) Hours of operation : Office Hours: 07:00 – 16:30 2: Hazard identification 2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Zinc metal in massive form is not classified as hazardous.
Classification according to Directive 67/548/EEC [DSD]
The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
See Section 11 for more detailed information on health effects and symptoms.
See Section 16 for the full text of the R phrases or H statements declared above.
2.2 Label elements Signal word Hazard statements
: No known significant effects or critical hazards
Precautionary statements Prevention Response Disposal 2.3 Other hazards Other hazards which do
: Hazards may be created by change in the physical condition of the metal, e.g. during melting. On
result in classification
heating zinc metal above 750oC freshly formed fumes of zinc oxide will be evolved. Zinc oxide fume
is associated with the onset of Metal Fume Fever, a reversible illness with flu-like symptoms. If the
lead content of the metal is over 1% and the physical state of the metal is altered, and dust or
fumes are generated, then the hazard statements are harmful by inhalation and if swallowed.
Danger of cumulative effects. Zinc may be taken up and bio-accumulated in invertebrates and other
3: Composition/information on ingredients Substance/mixture: Mono-constituent substance Classification Product/ingredient name Identifiers Regulation (EC) No. 67/548/EEC 1272/2008 [CLP]
There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section. Type [1] Substance classified with a health or environmental hazard.
Occupational exposure limits, if available, are listed in Section 8.
4: First aid measures 4.1 Description of first aid measures Eye contact
: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if irritation occurs.
Inhalation
: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
Skin Contact
: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation
Ingestion
: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Protection of first-aiders 4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye contact
: No significant irritation expected other than possible mechanical irritation.
Inhalation
: Zinc dust is discomforting to the respiratory tract when inhaled and initially acts as a
respiratory irritant. Zinc oxide fumes and vapour produced from high temperature processes can
produce ‘metal fume fever’. Symptoms include headache, nausea, chills, muscle aches, fever,
coughing, chest tightness and a metallic taste in the mouth. The onset of symptoms may be
delayed by up to 24 hours after exposure however normally symptoms present between 3 and 10
hours post exposure and can last for approximately 48 hours. Personnel may be particularly
susceptible to metal fume fever after a period of non-exposure.
Skin contact
: Material may be mildly discomforting to the skin. Zinc may irritate the skin and produce redness and
Ingestion
: Not normally a hazard due to the physical form of the product. Material is discomforting to the
digestive tract and may cause nausea, vomiting, headache, abdominal discomfort and diarrhea.
Convulsion, collapse and unconsciousness and death may occur in severe cases.
Over-exposure signs/symptoms Eye contact Inhalation Skin contact Ingestion 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician
: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have
Specific treatments 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing
: Use an extinguishing agent suitable for the surrounding fire. Dry sand or other inert material. Use
Unsuitable extinguishing : Water, foam or CO2 extinguishers 5.2 Special hazards arising from the substance or mixture Hazards from the substance or mixture Hazardous combustion
: Zinc + NaOH causes ignition. Oxidation of zinc by potassium proceeds with incandescence.
products
Residues from zinc dust /acetic acid reduction operations may ignite after long delay if discarded into
waste bins with paper. Incandescent reaction when Zinc and Arsenic or Tellurium, or Selenium are
combined. When hydrazine mononitrate is heated in contact with zinc, a flaming decomposition
occurs at temperatures a little above its melting point. Contact with acids and alkali hydroxides
(sodium hydroxide, postasium hydroxide, calcium hydroxide, etc.) results in evolution of hydrogen
with sufficient heat of reaction to ignite the hydrogen gas. Zinc foil ignites if traces of moisture are
present. It is water reactive and produces flammable gases on contact with water. Damp zinc metal
dust may heat spontaneously and ignite on exposure to air.
5.3 Advice for fire fighters
Special precautions Special protective
: Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European
equipment
standard EN 469 will provide a basic level of protection for chemical incidents.
6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency
: Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
personnel
appropriate personal protective equipment.
For emergency responders : See Section 8 for information on appropriate personal protective equipment. Follow good industrial
6.2 Environmental precautions
: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
6.3 Methods and materials for containment and cleaning up
: Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled
waste container. Dispose of via a licensed waste disposal contractor. Do not overheat molten zinc.
Extracted air containing metallic or metallic oxides should be cleaned before discharge. If product is
still hot after casting, cordon off area and allow cooling. If molten product spills, prevent spreading
with sand. Solid material should be picked up by shovel or by hand using leather gloves if
necessary. Ensure all chips or small particles are picked up and prevented from entering
6.4 Reference to other
: See Section 1 for emergency contact information.
sections
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
7: Handling and storage 7.1 Precautions for safe handling Protective measures
: Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin
sensitization problems should not be employed in any process in which this product is used. Keep
away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do
not breathe dust. Do not get in eyes. Do not ingest. Use mechanical lifting devices and tongs where
Advice on general
: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored
occupational hygiene
and processed. Workers should wash hands and face before eating, drinking and smoking. See
also Section 8 for additional information on hygiene measures.
7.2 Conditions for safe storage, : Use appropriate containment to avoid environmental contamination. Keep away from incompatibles including any incompatibilities
such as oxidizing agents, acids, alkalis and moisture. Store in a dry covered area. Cordon off stored
7.3 Specific end use(s) Recommendations 8: Exposure controls/personal protection
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any
available use-specific information provided in the Exposure Scenario(s).
8.1 Control parameters Occupational exposure limits Product/ingredient name Exposure limit values Engineering Controls
: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels
below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to
keep exposure to airborne contaminants below the exposure limit.
Personal Protection
: Safety glasses. Approved protective clothing (e.g. overalls and relevant footwear). Dust respirator. Be
sure to use an approved/certified respirator or equivalent. Leather gloves.
9: Physical and chemical properties Physical state and appearance Odor Threshold Molecular Weight pH (1% soln/water) Boiling Point Melting Point Flash point
: Not flammable. Very fine metal dusts may burn under ideal combustion
Vapor Pressure Vapor Density Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Solubility
: Insoluble in water, methanol, diethyl ether, n-octanol, acetone. Soluble in acids and alkalis.
Explosive Properties 10: Stability and reactivity Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability Possibility of hazardous
: Under normal conditions of storage and use, hazardous reactions will not occur. reactions
Conditions of instability
: Excess heat, incompatible materials, moisture.
Incompatible materials
: Strong acids, strong alkalis, strong oxidizers. Reaction with acids & strong alkalis may produce
potentially explosive hydrogen gas. The product may react violently with water to emit flammable but
Hazardous
: Under normal conditions of storage and use, hazardous decomposition products
decomposition products
should not be produced. Heating produces zinc oxide and small quantities of other metal oxides
such as lead and cadmium. Abrasion, handling or transport of material may generate inhalable or
11: Toxicological information 11.1 Information on toxicological effects Toxicokinetics Potential acute health effects Inhalation
: Zinc dust is discomforting to the respiratory tract when inhaled and initially acts as respiratory irritant.
Zinc oxide fumes and vapour produced from high temperature processes can produce ‘metal fume
fever’. Symptoms include headache, nausea, chills, muscle aches, fever, coughing, chest tightness
and a metallic taste in the mouth. The onset of symptoms may be delayed by up to 24 hours after
exposure however normally symptoms present between 3 and 10 hours post exposure and can
last for approximately 48 hours. Personnel may be particularly susceptible to metal fume fever after a
Ingestion
: Not normally a hazard due to the physical form of the product. Material is discomforting to the
digestive tract and may cause nausea, vomiting, headache, abdominal discomfort and diarrhea.
Convulsion, collapse and unconsciousness and death may occur in severe cases.
Skin contact
: Material may be mildly discomforting to the skin. Zinc may irritate the skin and produce redness and
Eye contact
: No significant irritation expected other than possible mechanical irritation. Potential chronic health
Potential chronic health 12: Ecological information Ecotoxicity Products of Biodegradation
: Possibly hazardous short term degradation products are not likely. However, long term degradation
Toxicity of the Products of Biodegradation Special Remarks on the Products : Not available of Biodegradation 13: Disposal considerations Waste Disposal Waste must be disposed of in accordance with legislation. 14: Transport information International transport regulations ADR/ADNR/IMDG/IATA : Not regulated. 15: Regulatory information 15.1Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation Substances of very high concern Other EU regulations Europe inventory 16: Other Information Indicates information that has changed from previously issued version. Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC)
EUH statement = CLP-specific Hazard statement
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Classification Justification
Zinc metal in massive form is not classified as hazardous
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. All information in this document shall be considered valid at the date of issuance only.
Pain has been noted as a constant companion of humanity since written records were kept. With the development of scientific method in the last 200 years understanding and control of this basic human experience has seemed possible. Yet even in this decade many still suffer in great distress with unrelieved pain. This is partly through a lack of knowledge but also through a lack of care and diligen
Clandestine Psychopathology: Unrecognized Dissociative Karni Ginzburg, PhD,* Eli Somer, PhD,† Gali Tamarkin, MSW,† and Lilach Kramer, MSW† A large scale survey among mental health professionals in Abstract: Surveys among Israeli mental health professionals found that Israel found that 63% of those interviewed had no experiencealmost half of them doubt the validity of dissociative dis
SAFETY DATA SHEET 
lead content of the metal is over 1% and the physical state of the metal is altered, and dust or
fumes are generated, then the hazard statements are harmful by inhalation and if swallowed.
Danger of cumulative effects. Zinc may be taken up and bio-accumulated in invertebrates and other
3: Composition/information on ingredients 
5: Firefighting measures 
8: Exposure controls/personal protection 
Convulsion, collapse and unconsciousness and death may occur in severe cases.
Skin contact