Microsoft word - msds002 pcf 27 5 42 60 1 4c un0351 _3_ aust amend 270510 _2_

PCF® SAFETY CARTRIDGES (RocKracker) 1.4C MATERIAL SAFETY DATA SHEET
REVISION DATE: 27-05-10

1. IDENTIFICATION

1.1 SUPPLIER
Company:
Street Address:
Telephone:
Facsimile:
EMERGENCY TELEPHONE NUMBER:
Mobile +61 0417 990 206 - 24hrs
1.2 PRODUCT
DESIGNATION
PRODUCT NAME: 27.5mm
UN Shipping Name:
Explosive
UN Number: 0351
Dangerous Goods Class: 1.4C
Subsidiary Risk:
Poisons Schedule Number: None
PERSONAL PROTECTIVE EQUIPMENT REQUIRED
This is the minimum personal protective equipment required during the use of PCFTM Safety Cartridges (RocKracker). Site specific personal protective equipment requirements also need to be adhered to. 1.5 PHYSICAL
DESCRIPTION
Plastic cylinder of varying diameters of which generally incorporate a wedge on one end and/or interference fitted plastic cap Each PCFTM Safety Cartridge (RocKracker) contains a blend of single and double based propellants. Warning:
Initiation of propellant may occur from excessive heating, exposure to static, friction and impact. G:\000_500-RockTek\RBS\RBS Users\MSDS_EPG_TDS\Updated with Baldivis Address\MSDS002 PCF 27 5 42 60 1 4C UN0351 (3) Aust PCF® SAFETY CARTRIDGES (RocKracker) 1.4C MATERIAL SAFETY DATA SHEET
REVISION DATE: 27-05-10

1.6 PHYSICAL
PROPERTIES
1.7 CHEMICAL
COMPONENTS
Component
Proportion %
HEALTH HAZARD INFORMATION
HEALTH EFFECTS - CARTRIDGE STRUCTURE UNCOMPROMISED
ACUTE EFFECTS - CARTRIDGE STRUCTURE UNCOMPROMISED
27.5mm, 42mm and 60mm PCFTM Safety Cartridge (RocKracker) No Risk - Humans unable to swallow cartridge No Risk - All irritating material is contained within the cartridge. No Risk - All irritating material is contained within the cartridge. No Risk - All irritating material is contained within the cartridge. CHRONIC EFFECTS - CARTRIDGE STRUCTURE UNCOMPROMISED
FIRST AID
All potentially hazardous substances are sealed within the cartridge and as such do not pose G:\000_500-RockTek\RBS\RBS Users\MSDS_EPG_TDS\Updated with Baldivis Address\MSDS002 PCF 27 5 42 60 1 4C UN0351 (3) Aust PCF® SAFETY CARTRIDGES (RocKracker) 1.4C MATERIAL SAFETY DATA SHEET
REVISION DATE: 27-05-10
HEALTH EFFECTS - CARTRIDGE STRUCTURE COMPROMISED
ACUTE HEALTH AFFECTS - CARTRIDGE STRUCTURE COMPROMISED
Propellant is toxic if swallowed. Considered an unlikely route of entry in commercial / industrial environments. Propellant may be irritating to the eyes. Propellant may be irritating to the skin. Repeated contact may lead to dermatitis. Propellant dust / particulate may be irritating to the upper respiratory tract and lungs. The decomposition vapours are harmful to the upper respiratory tract and lungs if inhaled in large CHRONIC HEALTH AFFECTS - CARTRIDGE STRUCTURE COMPROMISED
If the PCF® Safety Cartridge (RocKracker) structure is compromised, principal routes of exposure may be by skin contact and inhalation of propellant particles and / or generated dust. The principal hazard is related to the potential of fire and associated physical injury and potential toxic fume inhalation. One ingredient of the product has caused skin sensitisation reactions, shown as localised reddening and hives, or may produce respiratory sensitisation characterised by asthma-like symptoms and runny nose. As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice. Short term exposure by all routes is considered to be practically non-harmful. FIRST AID
 Give water (or milk to rinse out mouth), then provide liquid slowly and as much as the patient can comfortably drink. DO NOT give liquid to a person showing the signs of being sleepy or becoming unconscious.  Transport to hospital or doctor without delay. If the propellant comes into contact with the eyes:  Immediately hold the eyes open and wash continuously for at least 15 minutes with fresh running water. Ensure irrigation under the eyelids by occasionally lifting the upper and lower lids.  Transport to hospital or doctor without delay.  Skilled personnel should only undertake the removal of contact lenses after an eye If the propellant comes into contact with the skin:  Wash affected area thoroughly with water (and soap if available).  Seek medical attention in the event of irritation. If the propellant particles or combustion products are inhaled:  Lay patient down. Keep warm and rested.  If breathing is shallow or has stopped, ensure clear airway and apply resuscitation.

G:\000_500-RockTek\RBS\RBS Users\MSDS_EPG_TDS\Updated with Baldivis Address\MSDS002 PCF 27 5 42 60 1 4C UN0351 (3) Aust
PCF® SAFETY CARTRIDGES (RocKracker) 1.4C MATERIAL SAFETY DATA SHEET
REVISION DATE: 27-05-10

EXPOSURE STANDARDS
None assigned. Refer to Individual constituents Exposure Standards for Mixture
“Worst Case” computer aided prediction of vapour components/concentrations: Composite Exposure Standard for Mixture (TWA): If the breathing zone concentration of ANY of the components listed below is exceeded, “Worst Case” considerations deem the individual to be over-exposed. Breathing Zone
Component Ppm
Mixture Conc. (%)
Ingredient Data
 NITROCELLULOSE: No significant acute toxicological data identified in literature search.  NITROGLYCERIN: TOXICITY IRRITATION Oral(rat) LD50: 105mg/kg Skin(rabbit):500mg/24h – Mild Substance has been investigated as a tumorigen, mutagen and reproductive effector.  GRAPHITE: No significant acute toxicological data identified in literature search.
ADVICE TO DOCTORS
Treat symptomatically and as for exposure to nitro compounds. Delayed Pulmonary Oedema may result following exposure to nitrous oxides formed on SAFE HANDLING - STORAGE AND TRANSPORT

3.1 STORAGE
REQUIREMENTS
 Store PCFTM Safety Cartridges (RocKracker) in original packaging.  Keep packaging securely sealed until ready for use.  No smoking, naked lights, heat or ignition sources within 10 metres of storage location.  Store PCFTM Safety Cartridges (RocKracker) in a well ventilated, secure store.  Store in a cool dry place, do not store at temperatures above 65.5C (150F).  Store in an area away from other materials (ie: acids, alkalis, oxidizing/reducing agents and flammable chemicals).  Protect PCFTM Safety Cartridge ( RocKracker) packaging against physical damage.  Regularly check storage container and packaging. G:\000_500-RockTek\RBS\RBS Users\MSDS_EPG_TDS\Updated with Baldivis Address\MSDS002 PCF 27 5 42 60 1 4C UN0351 (3) Aust PCF® SAFETY CARTRIDGES (RocKracker) 1.4C MATERIAL SAFETY DATA SHEET
REVISION DATE: 27-05-10

3.2 STORAGE
INCOMPATIBILITY
 Store in an area away from other materials (ie: acids, alkalis, oxidizing/reducing agents and flammable chemicals).
 Avoid any contamination of the material contained in the PCF® Safety Cartridge (RocKracker) as it is very reactive and
any contamination is potentially hazardous.  Avoid contact with other explosives, pyrotechnics, solvents, adhesives, paints, cleaners and unauthorised metals, plastics, packaging equipment and materials.  Avoid contamination with acids, alkalis, reducing agents, amines and phosphorous.  Do not store in airtight containers to avoid the risk of the storage container rupturing violently in the event of
the PCF® Safety Cartridge (RocKracker) inside igniting when subjected to fire or extreme heat.

3.3 TRANSPORT
 PCF® Safety Cartridges (RocKracker) 27.5mm, 42mm and 60mm range are classified 1.4C UN0351 and as such may
be transported within regulatory guidelines.  PCF® Safety Cartridges (RocKracker) are approved for transport under the following codes:
1. The Australian Explosives Code (AEC) transport by road and rail. 2. United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. 3. IATA Dangerous Goods Regulations for airfreight.  PCF® Safety Cartridge (RocKracker) should be transported in the original packaging and segregated from strong acids,
In the event of a fire, clear area of personnel and move upwind. Propellants contained within the PCFTM Safety Cartridges (RocKracker) are sensitive to heat and will burn with rapidly Heating of cartridges may cause expansion or decomposition of the propellant leading to the ejection of cartridge capping. Avoid all excessive heat as it may cause a cartridge to initiate. Extinguishing a Fire: Nitrocellulose provides its own oxygen for combustion and the smothering action of foam or dry
chemical extinguishers may be ineffective. Therefore the use of water based extinguishing methods will be more
effective.
3.3 MINOR
In the event that propellant from a PCFTM Safety Cartridge (RocKracker) should be spilt the following action should be taken: Wear impervious gloves and safety glasses. Use spark free tools when handling propellant. Place spilled material in a clean, sealable, labelled container for disposal. G:\000_500-RockTek\RBS\RBS Users\MSDS_EPG_TDS\Updated with Baldivis Address\MSDS002 PCF 27 5 42 60 1 4C UN0351 (3) Aust PCF® SAFETY CARTRIDGES (RocKracker) 1.4C MATERIAL SAFETY DATA SHEET
REVISION DATE: 27-05-10

3.4 DISPOSAL
 PCF® Safety Cartridges (RocKracker) may be disposed of by burning or initiation but the operation may only be
performed under the control of a person trained in the safe destruction of explosives.  Consult manufacturer for disposal options. 4. CONTACT
AUSTRALIAN POISONS INFORMATION CENTRE (24 hour service 13 11 26)
EMERGENCY CONTACT
Notify Police and Fire Brigade as to location, material, quantity, UN Number and COMPANY CONTACT
RockTek Limited, Lot 1334 Stakehill Road, Baldivis, Western Australia, G:\000_500-RockTek\RBS\RBS Users\MSDS_EPG_TDS\Updated with Baldivis Address\MSDS002 PCF 27 5 42 60 1 4C UN0351 (3) Aust

Source: http://rocktek.com.au/wp-content/uploads/2012/05/MSDS-PCF-27.5-42-60-1.4C-UN-0351.pdf