Microsoft word - zest.doc

Product Name: ZEST
Page: 1 of 5
This version issued: August, 2013
Emergency Contact: 13 11 26 (Australia wide)
Section 1 - Identification of The Material and Supplier
E.D. Oates Pty Ltd
Phone: 1300 669 686 (business hours)
Trading as Citrus Resources
Fax: (03) 9359 9509
13-21 Maygar Boulevard
Email: customerservice@oates.com.au
Broadmeadows, Vic, 3047
Website: www.oateslaboratories.com.au
Chemical nature:
Water solution and emulsion of ingredients. Trade Name:
Product Use:
Mildly acidic toilet bowl and washroom cleaner. Creation Date:
August, 2013
This version issued:
August, 2013 and is valid for 5 years from this date.
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Xi, Irritating. Hazardous according to the criteria of SWA.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. Risk Phrases: R36, R66. Irritating to eyes. Repeated exposure may cause skin dryness or cracking.
Safety Phrases: S23, S36, S24/25. Do not breathe mists. Wear suitable protective clothing. Avoid contact with skin
and eyes.
SUSMP Classification: None allocated.
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
GHS Signal word: WARNING
HAZARD STATEMENT:
AUH066: Repeated exposure may cause skin dryness or cracking. H320: Causes eye irritation. H402: Harmful to aquatic life. PREVENTION
P102: Keep out of reach of children. P264: Wash contacted areas thoroughly after handling. P280: Wear protective gloves, protective clothing and eye or face protection. RESPONSE
P352: Wash with plenty of soap and water. P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313: If skin irritation occurs: Get medical advice. P337+P313: If eye irritation persists: Get medical advice. P391: Collect spillage. P370+P378: Not combustible. Use extinguishing media suited to burning materials. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool. DISPOSAL
P501: Dispose of small quantities and empty containers by wrapping with paper and putting in garbage. For larger quantities, if recycling or reclaiming is not possible, use a commercial waste disposal service. SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
E.D. Oates Pty Ltd ABN 61 004 329 462
13-21 Maygar Boulevard, Broadmeadows Vic 3047 Customer Service: 1300 669 686 | Website: www.oateslaboratories.com.au Oates is a division of GUD Holdings Ltd ABN 99 004 400 891
Product Name: ZEST
Page: 2 of 5
This version issued: August, 2013
Emergency Contact: 13 11 26 (Australia wide)
Emergency Overview
Physical Description & Colour: Viscous green liquid.
Odour: Lime fragrance.
Major Health Hazards: eye irritant.
Potential Health Effects
Inhalation:
Short Term Exposure: Available data indicates that this product is not harmful. In addition product is unlikely to
cause any discomfort or irritation.
Long Term Exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short Term Exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product may be irritating, but is unlikely to cause anything more than mild transient discomfort.
Long Term Exposure: Repeated exposure may cause skin dryness or cracking.
Eye Contact:
Short Term Exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and
watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Long Term Exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be
irritating to mucous membranes but is unlikely to cause anything more than transient discomfort.
Long Term Exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients
Ingredients
TWA (mg/m3) STEL
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible. The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly. SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
E.D. Oates Pty Ltd ABN 61 004 329 462
13-21 Maygar Boulevard, Broadmeadows Vic 3047 Customer Service: 1300 669 686 | Website: www.oateslaboratories.com.au Oates is a division of GUD Holdings Ltd ABN 99 004 400 891
Product Name: ZEST
Page: 3 of 5
This version issued: August, 2013
Emergency Contact: 13 11 26 (Australia wide)
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until
chemical is removed.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some
water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen
deficient (or both), fire gases. There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
Only small quantities of decomposition products are expected from this product at temperatures normally achieved in
a fire. This will only occur after heating to dryness.
Fire decomposition products from this product are not expected to be hazardous or harmful.
Extinguishing Media: Not combustible. Use extinguishing media suited to burning materials.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point:
Upper Flammability Limit:
Lower Flammability Limit:
Autoignition temperature:
Flammability Class:
Section 6 - Accidental Release Measures
Accidental release: This product is sold in small packages, and the accidental release from one of these is not
usually a cause for concern. For minor spills, clean up, rinsing to sewer and put empty container in garbage. Although
no special protective clothing is normally necessary because of occasional minor contact with this product, it is good
practice to wear impermeable gloves when handling chemical products. In the event of a major spill, prevent spillage
from entering drains or water courses and call emergency services.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Make sure that containers of this product are kept tightly closed. Make sure that the product does not come
into contact with substances listed under "Incompatibilities" in Section 10. Some liquid preparations settle or separate
on standing and may require stirring before use. Check packaging - there may be further storage instructions on the
label.
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
E.D. Oates Pty Ltd ABN 61 004 329 462
13-21 Maygar Boulevard, Broadmeadows Vic 3047 Customer Service: 1300 669 686 | Website: www.oateslaboratories.com.au Oates is a division of GUD Holdings Ltd ABN 99 004 400 891
Product Name: ZEST
Page: 4 of 5
This version issued: August, 2013
Emergency Contact: 13 11 26 (Australia wide)
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501
set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
SWA Exposure Limits
TWA (mg/m3) STEL
Exposure limits have not been established by SWA for any of the significant ingredients in this product. No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable
impervious elbow-length gloves and facial protection when handling this product. See below for suitable material
types.
Protective Material Types: There is no specific recommendation for any particular protective material type.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
handled commercially.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Viscous green liquid.
Odour: Lime
Boiling Point:
Freezing/Melting Point: Below
Volatiles:
Vapour Pressure:
2.37 kPa at 20°C (water vapour pressure). Vapour Density:
Specific Gravity: 1.10
Water Solubility:
pH: 1.0-2.0
Volatility: No
Odour Threshold: No
Evaporation Rate:
Coeff Oil/water Distribution: No
Autoignition temp:
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Keep containers tightly closed.
Incompatibilities: acids, oxidising agents.
Fire Decomposition: Only small quantities of decomposition products are expected from this product at
temperatures normally achieved in a fire. This will only occur after heating to dryness. Combustion forms carbon
dioxide, and if incomplete, carbon monoxide and possibly smoke. Water is also formed. Carbon monoxide poisoning
produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and
unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
E.D. Oates Pty Ltd ABN 61 004 329 462
13-21 Maygar Boulevard, Broadmeadows Vic 3047 Customer Service: 1300 669 686 | Website: www.oateslaboratories.com.au Oates is a division of GUD Holdings Ltd ABN 99 004 400 891
Product Name: ZEST
Page: 5 of 5
This version issued: August, 2013
Emergency Contact: 13 11 26 (Australia wide)
Section 11 - Toxicological Information
Local Effects:
Target Organs:
There is no data to hand indicating any particular target organs. Classification of Hazardous Ingredients
No ingredient mentioned in the HSIS Database is present in this product at hazardous concentrations. Section 12 - Ecological Information
This product is biodegradable. It will not accumulate in the soil or water or cause long term problems. However, until diluted or neutralised it will kill aquatic organisms it contacts due to low pH. Section 13 - Disposal Considerations
Disposal: Dispose of small quantities and empty containers by wrapping with paper and putting in garbage. For
larger quantities, if recycling or reclaiming is not possible, use a commercial waste disposal service.
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Emergency Contact: Phone 13 11 26 (Australia wide)
Acronyms:
Australian Code for the Transport of Dangerous Goods by Road and Rail (7th edition) Australian Inventory of Chemical Substances Safe Work Australia, formerly ASCC and NOHSC CAS number
Chemical Abstracts Service Registry Number International Agency for Research on Cancer R-Phrase Risk
Standard for the Uniform Scheduling of Medicines & Poisons UN Number United
Please read all labels carefully before using product. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. This MSDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous Chemicals - Code of Practice” (December 2011) Copyright Kilford & Kilford Pty Ltd, June, 2013. http://www.kilford.com.au/ Phone (02)9251 4532 End of Safety Data Sheet
SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
E.D. Oates Pty Ltd ABN 61 004 329 462
13-21 Maygar Boulevard, Broadmeadows Vic 3047 Customer Service: 1300 669 686 | Website: www.oateslaboratories.com.au Oates is a division of GUD Holdings Ltd ABN 99 004 400 891

Source: http://www.oateslaboratories.com.au/documents/downloads/msds/cr/zest.pdf