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Chemwatch msds 431815

OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 1 of 15
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE SYNONYMS
PROPER SHIPPING NAME
ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE PRODUCT USE
For use only as a wood preservative. Not suitable for any other purpose. Dangerous POISON.
Available ONLY for industrial and manufacturing purposes. To be used by or in accordancewith directions of accredited pest control officers. Operators to be trained in proceduresfor safe use of material. Material is mixed and used in accordance with manufacturersdirections Operators should be trained in procedures for safe use of this material.
SUPPLIER
Company: Osmose Australia P/LAddress:Cafrpirco Road Abn: 75 088 260 575Mt GambierSA, 5290AUSTelephone: (+61 8) 8723 1399Emergency Tel: 1800 039 008 (24 hours)Emergency Tel: +61 3 9573 3112Fax: 08 8723 0010 Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
Flammable.
Harmful in contact with skin.
continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 2 of 15
Section 2 - HAZARDS IDENTIFICATION .
Toxic by inhalation and if swallowed.
Danger of cumulative effects.
Irritating to skin.
May cause SENSITISATION by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.
HARMFUL-May cause lung damage if swallowed.
May produce discomfort of the eyes and respiratory tract*.
Limited evidence of a carcinogenic effect*.
Possible respiratory sensitiser*.
Vapours potentially cause drowsiness and dizziness*.
* (limited evidence) Keep locked up.
Keep away from sources of ignition. No smoking.
Avoid contact with eyes.
Wear suitable protective clothing.
In case of insufficient ventilation wear suitable respiratory equipment.
Use only in well ventilated areas.
Keep container in a well ventilated place.
To clean the floor and all objects contaminated by this material, use water anddetergent.
Keep container tightly closed.
This material and its container must be disposed of in a safe way.
Keep away from food, drink and animal feeding stuffs.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor orPoisons Information Centre.
If you feel unwell contact Doctor or Poisons Information Centre. (Show the labelif possible).
In case of accident by inhalation: remove casualty to fresh air and keep atrest.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Section 4 - FIRST AID MEASURES
SWALLOWED
If poisoning occurs, contact a doctor or Poisons Information Centre.
• IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.
• For advice, contact a Poisons Information Centre or a doctor.
Where Medical attention is not immediately available or where the patient ismore than 15 minutes from a hospital or unless instructed otherwise:• Induce vomiting with fingers down the back of the of the throat, ONLY IFCONSCIOUS.
• Lean patient forward or place on left side (head-down position if possible) tomaintain open airway and prevent aspiration.
continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 3 of 15
Section 4 - FIRST AID MEASURES .
NOTE: Wear a protective glove when inducing vomiting by mechanical means.
• In the mean time, qualified first-aid personnel should treat the patientfollowing observation and employing supportive measures as indicated by thepatient's condition.
• If the services of a medical officer or medical doctor are readily available,the patient should be placed in his/her care and a copy of the MSDS should beprovided. Further action will be the responsibility of the medical specialist.
• If medical attention is not available on the worksite or surroundings send thepatient to a hospital together with a copy of the MSDS.
If this product comes in contact with the eyes:• Immediately hold eyelids apart and flush the eye continuously with runningwater.
• Ensure complete irrigation of the eye by keeping eyelids apart and away fromeye and moving the eyelids by occasionally lifting the upper and lower lids.
• Continue flushing until advised to stop by the Poisons Information Centre or adoctor, or for at least 15 minutes.
• Transport to hospital or doctor without delay.
• Removal of contact lenses after an eye injury should only be undertaken byskilled personnel.
If skin or hair contact occurs:• Immediately flush body and clothes with large amounts of water, using safetyshower if available.
• Quickly remove all contaminated clothing, including footwear.
• Wash skin and hair with running water. Continue flushing with water untiladvised to stop by the Poisons Information Centre.
• Transport to hospital, or doctor.
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed,where possible, prior to initiating first aid procedures.
• Apply artificial respiration if not breathing, preferably with a demand valveresuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR ifnecessary.
• Transport to hospital, or doctor.
NOTES TO PHYSICIAN
For acute or short term repeated exposures to petroleum distillates or relatedhydrocarbons:• Primary threat to life, from pure petroleum distillate ingestion and/orinhalation, is respiratory failure.
• Patients should be quickly evaluated for signs of respiratory distress (e.g.
cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen.
Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mmHg) should be intubated.
• Arrhythmias complicate some hydrocarbon ingestion and/or inhalation andelectrocardiographic evidence of myocardial injury has been reported;intravenous lines and cardiac monitors should be established in obviouslysymptomatic patients. The lungs excrete inhaled solvents, so thathyperventilation improves clearance.
• A chest x-ray should be taken immediately after stabilisation of breathing andcirculation to document aspiration and detect the presence of pneumothorax.
• Epinephrine (adrenalin) is not recommended for treatment of bronchospasmbecause of potential myocardial sensitisation to catecholamines. Inhaled continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 4 of 15
Section 4 - FIRST AID MEASURES .
cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferredagents, with aminophylline a second choice.
• Lavage is indicated in patients who require decontamination; ensure use ofcuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: MedicalToxicology]For acute or short term repeated exposures to organic tin compounds:• Severe exposure results in tinnitus, deafness, memory loss, psychosis, coma,disorientation and respiratory depression after a latent period of 1-3 days.
• Permanent neurologic sequelae include extrapyramidal hyperkinesia.
• The material produces erythmetous skin lesions.
• Management is primarily supportive.
• British Anti-Lewisite and d-penacillamine are not effective as chelators.
[Ellenhorn and Barceloux: Medical Toxicology] Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
• Foam.
• Dry chemical powder.
• BCF (where regulations permit).
• Carbon dioxide.
• Water spray or fog - Large fires only.
FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• May be violently or explosively reactive.
• Wear full body protective clothing with breathing apparatus.
• Prevent, by any means available, spillage from entering drains or watercourse.
• Consider evacuation (or protect in place).
• If safe, switch off electrical equipment until vapour fire hazard removed.
• Use water delivered as a fine spray to control fire and cool adjacent area.
• Avoid spraying water onto liquid pools.
• DO NOT approach containers suspected to be hot.
• Cool fire exposed containers with water spray from a protected location.
• If safe to do so, remove containers from path of fire.
• Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
• Liquid and vapour are flammable.
• Moderate fire hazard when exposed to heat or flame.
• Vapour forms an explosive mixture with air.
• Moderate explosion hazard when exposed to heat or flame.
• Vapour may travel a considerable distance to source of ignition.
• Heating may cause expansion or decomposition leading to violent rupture ofcontainers.
• On combustion, may emit toxic fumes of carbon monoxide (CO).
May emit poisonous fumes.
Other combustion products includehighly toxicmetal oxidesi.e.
tin FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,chlorine bleaches, pool chlorine etc. as ignition may result continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 5 of 15
Section 5 - FIRE FIGHTING MEASURES .
Personal Protective Equipment
Respirator:Type A-P Filter of sufficient capacity Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
DO NOT touch the spill material• Remove all ignition sources.
• Clean up all spills immediately.
• Avoid breathing vapours and contact with skin and eyes.
• Control personal contact by using protective equipment.
• Contain and absorb small quantities with vermiculite or other absorbentmaterial.
• Wipe up.
• Collect residues in a flammable waste container.
MAJOR SPILLS
DO NOT touch the spill materialPollutant• Clear area of personnel and move upwind.
• Alert Fire Brigade and tell them location and nature of hazard.
• May be violently or explosively reactive.
• Wear full body protective clothing with breathing apparatus.
• Prevent, by any means available, spillage from entering drains or watercourse.
• Consider evacuation (or protect in place).
• No smoking, naked lights or ignition sources.
• Increase ventilation.
• Stop leak if safe to do so. Water spray /fog may be used to disperse vapour.
• Contain or absorb spill with sand, earth or vermiculite.
• Use only spark-free shovels and explosion proof equipment.
• Collect recoverable product into labelled containers for recycling.
• Collect solid residues and seal in labelled drums for disposal.
• Wash area and prevent runoff into drains.
• After clean up operations, decontaminate and launder all protective clothingand equipment before storing and re-using.
• If contamination of drains or waterways occurs, advise emergency services.
PROTECTIVE ACTIONS FOR SPILL
continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 6 of 15
Section 6 - ACCIDENTAL RELEASE MEASURES .
From IERG (Canada/Australia)Isolation Distance FOOTNOTES1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on either side of the predominant wind direction, resulting in a crosswind protective action distance equal to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill and working away from the site in the downwind direction. Within the protective action zone a level of vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high probability of localised wind reversal may expose nearly all persons without appropriate protection to life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 131 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
EMERGENCY RESPONSE PLANNING GUIDLINES (ERPG)
The maximum airborne concentration below which it is believed that nearly allindividuals could be exposed for up to one hour WITHOUT experiencing or developing irreversible or other serious effects or symptoms which couldimpair an individual's ability to take protective action is: other than mild, transient adverse effectswithout perceiving a clearly defined odour is: continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 7 of 15
Section 6 - ACCIDENTAL RELEASE MEASURES .
American Industrial Hygiene Association (AIHA) Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
DO NOT allow clothing wet with material to stay in contact with skin• Avoid all personal contact, including inhalation.
• Wear protective clothing when risk of overexposure occurs.
• Use in a well-ventilated area.
• Prevent concentration in hollows and sumps.
• DO NOT enter confined spaces until atmosphere has been checked.
• Avoid smoking, naked lights or ignition sources.
• Avoid generation of static electricity.
• DO NOT use plastic buckets.
• Earth all lines and equipment.
• Use spark-free tools when handling.
• Avoid contact with incompatible materials.
• When handling, DO NOT eat, drink or smoke.
• Keep containers securely sealed when not in use.
• Avoid physical damage to containers.
• Always wash hands with soap and water after handling.
• Work clothes should be laundered separately.
• Use good occupational work practice.
• Observe manufacturer's storing and handling recommendations.
• Atmosphere should be regularly checked against established exposure standardsto ensure safe working conditions.
SUITABLE CONTAINER
• Metal can or drum• Packaging as recommended by manufacturer.
• Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid contamination of water, foodstuffs, feed or seed.
Avoid storage with oxidisers STORAGE REQUIREMENTS
• Store in original containers in approved flammable liquid storage area.
• DO NOT store in pits, depressions, basements or areas where vapours may betrapped.
• No smoking, naked lights, heat or ignition sources.
• Keep containers securely sealed.
• Store away from incompatible materials in a cool, dry, well-ventilated area.
• Protect containers against physical damage and check regularly for leaks.
• Observe manufacturer's storing and handling recommendations.
continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 8 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of vapour components/concentrations: Composite Exposure Standard for Mixture (TWA) (mg/m³): 900 mg/m³If the breathing zone concentration of ANY of the components listed below isexceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m³ Mixture Conc: (%) INGREDIENT DATA
Exposure limits with "skin" notation indicate that vapour and liquid may beabsorbed through intact skin. Absorption by skin may readily exceed vapourinhalation exposure. Symptoms for skin absorption are the same as forinhalation. Contact with eyes and mucous membranes may also contribute tooverall exposure and may also invalidate the exposure standard.
CAUTION: This substance has been classified by the ACGIH as A3 Animal Carcinogen(at relatively high doses)OEL TWA: 14 ppm, 100 mg/m³ TLV TWA: 0.1 mg/m³ Organic compounds Skin;A4 [ACGIH]TLV STEL: 0.2 mg/m³ Organic compounds Skin;A4 [ACGIH]tin organic compounds, as Sn (A.Wt: 118.69)ES TWA: 0.1 mg/m³; STEL: 0.2 mg/m³ SKINTLV TWA: 0.1 mg/m³; STEL: 0.2 mg/m³ A4OES TWA: 0.1 mg/m³; STEL: 0.2 mg/m³ SKINNOTE: This substance has been classified by the ACGIH as A4 NOT classifiable ascausing Cancer in humans.
Exposure limits with "skin" notation indicate that vapour and liquid may beabsorbed through intact skin. Absorption by skin may readily exceed vapourinhalation exposure. Symptoms for skin absorption are the same as forinhalation. Contact with eyes and mucous membranes may also contribute tooverall exposure and may also invalidate the exposure standard.
IDLH Level: 25 mg/m³ (as Sn)The no/lowest-observed-adverse-effect levels (NOAELs or LOAELs) in inhalationstudies involving tri-n-butyltin chloride and bromide are 0.3-0.4 ppm (2-4mg/m³) based on changes in the lungs, heart, liver, kidneys, nervous system andreproductive system in rodents. Oral administration of organotin compounds hasinduced toxicity in a number of differing organ systems, organs and lungs. TheLOAEL for triethyltin bromide was 0.4 mg triethyltin/kg/day as 5 ppm in drinkingwater. The LOAELs for the most critical organ sites in rats (i.e. the cellularimmune response and CNS effects) are 0.15 and 0.23 mg/tin/kg body weight/day.
Experience with ingested tri- and diethyltins in the treatment of staphylococcalinfections, osteomyelitis, anthrax and acne suggests that humans react in a continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 9 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION .
manner similar to rodents, but that the human is more sensitive to absorbedorganic tin. The recommended TLV-TWA is thought to minimise the potential foradverse effects on immune function and the central nervous system. A STEL isalso recommended to minimise acute symptoms such as eye and respiratory tractirritation, headaches and/or nausea. Based on an exposure to 0.1 mg/m³, a 70-kgworker breathing 10 m3 of air/8hr workday and assuming complete retention of theinhaled dose, would receive a daily exposure of 14.3 ug tin/kg body weight of anorganotin compound. A skin notation was recommended based on animal data and thepotential danger of enhanced absorption due to damaged skin present in manyexposed workers.
Dusts not otherwise classified, as inspirable dust;ES TWA: 10 mg/m³ Dusts not otherwise classified, as inspirable dust;ES TWA: 10 mg/m³ PERSONAL PROTECTION
• Safety glasses with side shields• Chemical goggles.
• Contact lenses pose a special hazard; soft lenses may absorb irritants and alllenses concentrate them.
HANDS/FEET
• Barrier cream with polyethylene glovesorWear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber OverallsandRubber apronorPVC apron• Ensure that there is ready access to eye wash unitEnsure there is ready access to an emergency shower ENGINEERING CONTROLS
Concentrate material is measured and mixed, preferably outdoors, in proportionsas recommended by manufacturer.
Use in a well-ventilated areaGeneral exhaust is adequate under normal operating conditions. Local exhaustventilation may be required in specific circumstances. If risk of overexposureexists, wear approved respirator. Correct fit is essential to obtain adequateprotection. Provide adequate ventilation in warehouse or closed storage areas.
continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 10 of 15
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION .
Air contaminants generated in the workplace possess varying "escape" velocitieswhich, in turn, determine the "capture velocities" of fresh circulating airrequired to effectively remove the contaminant.
evaporating from tank (in still air).
aerosols, fumes from pouring operations, intermittent containerfilling, low speed conveyer transfers,welding, spray drift, plating acidfumes, pickling (released at lowvelocity into zone of activegeneration)direct spray, spray painting in shallow booths, drum filling, conveyer loading,crusher dusts, gas discharge (activegeneration into zone of rapid airmotion)grinding, abrasive blasting, tumbling, high speed wheel generated dusts(released at high initial velocity intozone of very high rapid air motion).
Within each range the appropriate value depends on: favourable to capture2: Contaminants of low toxicity or of nuisance value only.
3: Intermittent, low production.
Simple theory shows that air velocity falls rapidly with distance away from theopening of a simple extraction pipe. Velocity generally decreases with thesquare of distance from the extraction point (in simple cases). Therefore theair speed at the extraction point should be adjusted, accordingly, afterreference to distance from the contaminating source. The air velocity at theextraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) forextraction of solvents generated in a tank 2 meters distant from the extractionpoint. Other mechanical considerations, producing performance deficits withinthe extraction apparatus, make it essential that theoretical air velocities aremultiplied by factors of 10 or more when extraction systems are installed orused.
In confined spaces where there is inadequate ventilation, wear full-face airsupplied breathing apparatus Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Straw coloured flammable liquid with a slight solvent odour;does not mix with water.
continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 11 of 15
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES .
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Floats on water.
Toxic or noxious vapours/gas.
Relative Vapour Density (air=1): Not available log Kow (Sangster 1997): 6.5log Kow : 3.48-6.5 Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
• Presence of incompatible materials.
• Product is considered stable.
• Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED

Considered an unlikely route of entry in commercial/industrial environmentsThe concentrate ishighly discomfortingandtoxicif swallowedIngestion may result in nausea, pain, vomiting. Vomit entering the lungs byaspiration may cause potentially lethal chemical pneumonitis.
The liquid produces a high level of eye discomfort and is capable of causingpain and severe conjunctivitis. Corneal injury may develop, with possiblepermanent impairment of vision, if not promptly and adequately treated.
The vapour ismildlydiscomfortingto the eyes continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 12 of 15
Section 11 - TOXICOLOGICAL INFORMATION .
The concentrate isdiscomfortingto the skinif exposure is prolongedand the material contains a component that may be absorbed through the skinand may causein some cases, sensitisationi.e.
skin sensitisationToxic effects may result from skin absorptionBare unprotected skin should not be exposed to this materialThe material may cause severe skin irritation after prolonged or repeatedexposure and may produce on contact skin redness, swelling, the production ofvesicles, scaling and thickening of the skin. Repeated exposures may producesevere ulceration.
The vapour is discomfortingto the upper respiratory tractif inhaledInhalation hazard is increased at higher temperatures.
Acute effects from inhalation of high vapour concentrations may be chest andnasal irritation with coughing, sneezing, headache and even nausea.
The mist ishighly discomfortingandharmfulif inhaled CHRONIC HEALTH EFFECTS
Principal routes of exposure are usually by skin contact with the material skin contactwith the material in solution and inhalation of vapour Osmose Protim - LOSP H3 (235WR) Wood Preservative
None assigned. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effectsof Chemical Substances Oral (man) TDLo: 3570 mg/kgOral (rat) LD50: >5000 mg/kgInhalation (rat) LC50: >5000 mg/m3/4h tributyltin benzoate:Oral (rat) LD50: 132 mg/kg Inhalation (rat) LD50: 300 mg/m3/4hDermal (rat) LD50: 1000 mg/kgADI: 0.03 mg/kg/day continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 13 of 15
Section 11 - TOXICOLOGICAL INFORMATION .
Unreported (human) LDLo >4000 mg/kgOral (rat) LD50: 383 mg/kgInhalation (rat) LC50: 485 mg/m3Dermal (rat) LD50: 1750 mg/kgDermal (mouse) LD50: >10000 mg/kgOral (rabbit) LD50: 4000 mg/kgDermal (rabbit) LD50: >2000 mg/kgOral (g.pig) LD50: 4000 mg/kg The substance is classified by IARC as Group 3:NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Oral (rat) LD50: 430-4000 mg/kg *Oral (mouse) LD50: 540-2960 mg/kg * Oral (rat) LD50: 1479 mg/kg [AgrEvo]ADI: 0.05 mg/kg for nominal cis-trans 40:60 and 25:75 isomers only[ * The Pesticides Manual, Incorporating The Agrochemicals Handbook, 10thEdition, Editor Clive Tomlin, 1994, British Crop Protection Council] Section 12 - ECOLOGICAL INFORMATION
No data for Osmose Protim - LOSP H3 (235WR) Wood Preservative.
Refer to data for ingredients, which follows: DO NOT discharge into sewer or waterways.
No data for tributyltin naphthenate.
DICHLOFLUANIDE:Hazardous Air Pollutant: No Not toxic to beesIn plants dichlofluanid is metabolised to dimethylsulfanilide which isthen demethylated/ hydroxylated.
PERMETHRIN:Hazardous Air Pollutant: NoFish LC50 (96hr.) (mg/l): 0.0006-0.0log Kow (Sangster 1997): 6.5log Pow (Verschueren 1983): 3.48 * Muir et al. 1994 Aquatic Toxicology 29(3/4)223-240 Toxicity Class WHO: II (Ambush); III (Outflank) continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 14 of 15
Section 12 - ECOLOGICAL INFORMATION .
In soil and water degradation rapid:DT50 in soil <38 days (pH 4.2-7.7 o.m. 1.3-51.3%)Synthetic pyrethroids are examples of optimised insecticidal activity,selectivity and tailored environmental persistence. Through modifications ofboth acid and alcohol portions of the ester, compounds of desired residualactivity have been synthesised whilst maintaining a biodegradable ester linkage.
These compounds are generally very toxic to crustaceans and fish in laboratorybioassays. Under field conditions, however, the residues are tightly bound insediment, and ingested residues are readily metabolised. Their toxicity innatural systems are generally less than laboratory test data might indicate.
They are generally non-persistent in the environment.
Pyrethrins are generally unstable in the presence of light, are hydrolysedrapidly under alkaline conditions and oxidise rapidly in air. Vapour phasepyrethrins may combine chemically with ozone to produce hydroxy radicals.
Because agricultural dose rates are low and biological degradation is generallyrapid, residues are unlikely to attain significant levels. Permethrin disappearsfrom ponds and streams within 6-24 hours, pond sediments within 7 days andfoliage and forest soil within 58 days. Pyrethroids are highly toxic to fish;the bioaccumulation factor of cypermethrin in fish is approximately 1000 whenmeasured experimentally, although the potential for significant toxicity is notreached in fields. Under aerobic conditions in soil, permethrin degrades in arelatively short time (half-life 28 days).
Drinking Water Standards:pesticide 0.1 ug/l (UK max.)Oral (chicken) LD50: 7000 mg/kgOral (quail) LD50: 13500 mg/kgOral (duck) LD50: 11300 mg/kg Section 13 - DISPOSAL CONSIDERATIONS
• Recycle wherever possible. Special hazards may exist - specialist advice maybe required.
• Consult manufacturer for recycling options.
• Consult State Land Waste Management Authority for disposal.
• Incinerate residue at an approved site.
• Decontaminate empty containers.
• Observe all label safeguards until containers are cleaned and destroyed.
• Puncture containers to prevent reuse and bury at an authorised land fill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name: ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE Dangerous Goods Class: 6.1UN/NA Number: 3019 continued.
OSMOSE PROTIM - LOSP H3 (235WR) WOOD PRESERVATIVE
ChemWatch Material Safety Data Sheet
CHEMWATCH 431815
Issue Date: Thu 11-Mar-2004
CD 2004/3 Page 15 of 15
Section 14 - TRANSPORTATION INFORMATION .
ADR Number: 63Packing Group: IIILabels Required: toxic,flammable liquidAdditional Shipping Information: International Transport Regulations: IMO: 6.1, 6.1 Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
REGULATIONS
Australian Inventory of Chemical Substances (NICNAS) applies to the following ingredients: kerosene (CAS: 8008-20-6) tributyltin naphthenate (CAS: 85409-17-2) dichlofluanide (CAS: 1085-98-9) permethrin (CAS: 52645-53-1) No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 57608-04-5). applies to the following ingredients: No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 93388-66-0). applies to the following ingredients: No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 63364-00-1). applies to the following ingredients: No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 57608-04-5). applies to the following ingredients: No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 60018-94-2). applies to the following ingredients: No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 54774-45-7).
No data available for permethrin (CAS: 75497-64-2). applies to the following ingredients: No data available for permethrin (CAS: 54774-45-7).
Section 16 - OTHER INFORMATION
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Issue Date: Thu 11-Mar-2004Print Date: Tue 12-Oct-2004

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