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Msds eznatural powder.pdf

11652 Monarch Street Garden Grove CA 92841 562-598-3966 Fax 598-8096. Material Safety Data Sheet POLYMER NATURAL Page 1 of 4
Revised Date: 7/18/2006 | Replaces Date: 1/28/2005
MSDS#: KIP112900-PN2
Section 1 – Identification of the Substance/Preparation and of the
Company/Undertaking
Product Name: POLYMER NATURAL MSDS#: KIP112900-PN2
Chemical Name:
N/A MSDS Initial Approval Date: 12/02/2000 MSDS Prepared by:
BSQ
Family: ACRYLIC POLYMER Manufacturer: KEYSTONE INDUSTRIES
616 Hollywood Ave, Cherry Hill, NJ 08002
Product Use: NAIL POLYMER Emergency Phone Numbers: (800) 535 - 5053
Product #: 1000216, 1001528, 1001521, 1001553, 4021107,
1001612, 1001607, 1000928, 1000731, 1001559, 1001378
Information Contacts: ( 856 ) 663 - 4700
Section 2 - Composition/Information on Ingredients Section 2 -
Composition/Information on Ingredients
Chemical Identity CAS Numbers EINECS# INCI Name Exposure Limits Carcinogen %
OSHA ACGIH
TWA/STEL TWA/STEL IARC/NTP/OSHA
Poly (ethyl methacrylate) 9003-42-3 N/E Polyethylmethacrylate N/E N/E Not Listed 65-99
Poly (methyl methacrylate) 9011-14-7 N/E Polymethyl M ethacrylate N/E N/E Group 3/no/no 0-35
Titanium Dioxide 13463-67-7 236-675-5 Titanium dioxide/CI77891 15 mg/m3 10 mg/m3 Group 3/no/no 0-1
Dibenzoyl Peroxide 94-36-0 202-327-6 Benzoyl peroxide 5 mg/m3 5 mg/m3 3/no/no 0-1
D&C Red # 7 5281-04-9 226-109-5 CI15850 N/E N/E Not Listed 0-0.25
N/E - None Established
N/R - Not Reviewed
N/DA - No Data Available
N/A - Not Applicable
Hazard Symbols: Xi Risk Phrases: R36/37/38 Safety Phrases: S18, S22, S24/25, S38
This product is not considered hazardous by OSHA Hazard Communication Standard.
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
This information may be based on findings from related or similar materials.
• May cause allergic skin reaction.
• May cause eye irritation.
• Dust may cause irritation of the nose, throat, and lungs.
• This product may contain particulate, not otherwise classified (Nuisance Dust)
Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry Eyes or skin (No absorption); inhalation of dust.
Eye Higher concentration can irritate eyes. May cause eye irritation or damage.
Skin Repeated or prolonged exposure may cause allergic skin rashes.
Ingestion Higher concentration can irritate respiratory system.
Inhalation Possible temporary discomfort due to inhalation of dust concentration above the permissible exposure limit.
Dust
may cause irritation of the nose, throat, and lungs.
Sub-Chronic Effects For Polymer: OSHA classifies this material as Particulates, Not Otherwise Classified. Eyes,
skin and Respiratory
tract may be irritated by gross overexposure to Particulates, Not Otherwise Classified, no matter how they are
generated. Avoid inhalation of dust. Keep dust out of eyes to prevent possible irritation.
For decomposition product: Methyl Methacrylate Monomer; Liquid or high vapor concentration can irritate eyes,
respiratory system and cause skin rashes. Prolonged exposure can lead to headaches, nausea, staggering gait,
confusion, drowsiness and unconsciousness. Repeated and prolonged over exposure may cause permanent brain
and nervous system damage, allergic skin rashes, eye corrosion and permanent injury, as well as changes in liver
and kidney function or damage.
For Benzoyl Peroxide: repeated or prolonged contact may cause skin sensitization.
11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
NOTE: Refer to Section 11, Toxicological Information for Details
Section 4 - First Aid Measures
First Aid for Eye Flush with water for 15 minutes, including under eyelids. Get medical help if discomfort
persists.
First Aid for Skin Wash with soap and water. Get medical help if discomfort persists.
First Aid for Inhalation Remove to fresh air. Get medical help if discomfort persists.
First Aid for Ingestion Rinse mouth out with water. Call doctor if amount was large.
Material Safety Data Sheet POLYMER NATURAL Page 2 of 4
Revised Date: 7/18/2006 | Replaces Date: 1/28/2005
MSDS#: KIP112900-PN2
Section 5 - Fire Fighting Measures
Flash Point(°F/°C) Flammable Limit(vol%) Auto-ignition Temperature(vol%)
TAG Closed: 580ºF/304ºC N/A N/E
Method:
Extinguishing Media: Water, carbon dioxide, dry chemical.
Fire Fighting
Instructions:
Avoid extinguishing methods that generate dust clouds. Water streams can disperse dust into
air, producing a fire hazard and possible explosion hazard. Fire-fighters should wear self -
contained breathing apparatus.
Unusual Hazards: Polymer dust is combustible, explosive limits of the polymer particles suspended in air
are
approximately those of coal dust.
Section 6 - Accidental Release Measures
Spill or Release
Procedures
Sweep up to avoid slipping hazard. Keep airborne particulates at a minimum when cleaning
up spills.
Section 7 - Handling and Storage
Handling Observe precautions found on the label. Wash face and hands thoroughly with soap and water
after handling and before eating, drinking or smoking.Avoid prolonged or repeated contact
with skin. Avoid contamination. Use only with adequate ventilation.
Storage Store in cool, dry place away from heat, sparks, flame and direct sunlight. Close container
after each use. Ground all metal conrainers when transferring. Use explosion-proof equipment
Store away from combustibles and incompatible materials.
Explosion Hazard Polymer dust is combustible, explosive limits of the polymer particles suspended in air
are
approximately those of coal dust.
Section 8 - Exposure Controls / Personal Protective Equipment
Engineering Controls Use good local exhaust at processing equipment, including buffers, sanders, grinders
and
polishers . High temperature processing equipment should be well ventilated. Use explosionproof
equipment.Provide ventilation if necessary to control exposure levels below airborne
exposure limits.
Personal Protective Equipment
General Dust collectors are recommended for handling powder in bulk.
Eye/ Face Protection Use safety glasses and have eye flushing equipment immediately available.
Skin Protection Minimize contamination by following good industrial practice. Wearing nitrile, neoprene,
pvc,
latex ot other impermeable gloves is recommended.
Respiratory Protection Avoid breathing dust and mist. Use dust mask.
11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
Section 9 - Physical and Chemical Properties
Appearance Odor & Odor Threshold PH Specific Gravity Viscosity % Volatile
Fine, white powder Faint odor in bulk. N/A N/A N/A N/A
Boiling Point/ Decomposition Octanol/Water Vapor Vapor Evaporation Ignition Solubility
Freezing Point
Temperature Partitioning Coefficient
Log Po/w
Pressure: Density Rate In Water
(20°C)
N/A N/A N/A N/A N/A N/A N/A insoluble
Flash Point(°F/°C) Flammable Limit(vol%) Auto-ignition Temperature(vol%)
TAG Closed: 580ºF/304ºC N/A N/E
Section 10 - Stability and Reactivity
Stability:
Stable
Hazardous Decomposition Products: methacrylate monomers
Incompatibility (Materials to Avoid): Strong oxidizing agents
Conditions to Avoid: Heating above 240 deg C , 464 deg F Hazardous Polymerization: will not occur
Section 11 - Toxicological Information
Material Safety Data Sheet POLYMER NATURAL Page 3 of 4
Revised Date: 7/18/2006 | Replaces Date: 1/28/2005
MSDS#: KIP112900-PN2
Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Irritation - skin Irritation - Eye
LD50 Oral (Rat) :
7990mg/kg
LD50 Dermal (Rabbit):
35,500 mg/kg
LC50 Inhalation (Rat) : >12,500
to 16,500 ppm for 0.5 hours
mild mild
Since this product contains a very low concentration of active components, the primary toxicological information is
derived from the copolymers.
Further hazardous properties cannot be excluded. The product should be handled with care when dealing with
chemicals.
Sensitization Mutagenicity Sub-chronic Toxicity
No information available No information available No information available
RTECS#: 9011-14-7: TR0400000
Section 12 - Ecological Information
Ecotoxicological Information
Acute Toxicity
to Fish
Acute Toxicity
to Invertebrates
Acute Toxicity
to Algae
Bioconcentration Toxicity to Sewage Bacteria
Flathead minnows and goldfish TLm24 : 420 ppm
Bluegills TLm24 : 368 ppm
N/DA N/DA N/DA N/DA
Chemical Fate Information
Biodegradability
N/DA
Chemical Oxygen Demand N/DA
To the best of our knowledge, the ecotoxocological and chemical fate properties have not been thoroughly investigated.
Do not allow to enter drinking water supplies, wastewater, or soil.
Section 13 - Disposable Considerations
May be disposed of in a landfill or incinerated. Follow Federal, State and Local regulations for disposal. For EU
Member States, please
refer to any relevant Community provisions relating to waste. In their absence, it is useful to remind the user that
national or regional provisions may
11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
be in force.
Section 14 - Transport Information
DOT (49 CFR 172)
Proper Shipping Name: Non-Regulated Material
Identification Number: N/A
Marine Pollutant: No
Special Provisions: N/A
Emergency Response Guidebook (ERG) #: N/A
IATA (DGR):
Proper Shipping Name: Non-Regulated Material
Class or Division: N/A
UN or ID Number: N/A
Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name: Non-Regulated Material
Class or Division: N/A
UN or ID Number: N/A
Special Provisions & Stowage/Segregation: None
Emergency Schedule (EmS)#:
Other Information: Flash point > 100ºC
Section 15 - Regulatory Information
US Federal Regulations
Clean Air Act: HAP/ODS This product contains the following hazardous air pollutants (HAP's) or ozone dipleting
substances
(ODS's), as defined by the U. S. Clean Air Act:
• NONE
Clean Water Act: Priority Pollutant This product contains the following chemicals listed under the U.S. Clean Water
Act Priority
Pollutant List:
• NONE
FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging and/ or other
applications as an indirect food additive.
Occupational Safety and Health Act This product is not considered a hazardous chemical under the OSHA Hazard
Communication
Standard.
RCRA This product contains no chemicals considered to be hazardous waste under RCRA ( 40
CFR 261).
SARA Title III: Section 302 (TPQ) This product contains no chemicals regulated under Sec. 302 as extremely
hazardous
substances.
Material Safety Data Sheet POLYMER NATURAL Page 4 of 4
Revised Date: 7/18/2006 | Replaces Date: 1/28/2005
MSDS#: KIP112900-PN2
SARA Title III: Section 302 (RQ) This product contains no chemicals regulated under Sec. 304 as extremely hazardous
chemicals for emergency release notification ( "CERCLA " List).
SARA Title III: Section 311-312: This product does not contain hazardous substances under the OSHA Hazard
Communication
Standard, and is not regulated under Section 311-312 (40 CFR 370).
SARA Title III: Section 313: This product contains the following chemicals outlined in SARA Title III: Section 313:
• Benzoyl Peroxide CAS #94-36-0.
TSCA Section 8(b): Inventory:
TSCA Significant New Use Rule:
This product contains chemicals listed on the TSCA inventory or otherwise complies with TSCA
premanufacture notification requirements.
None of the chemicals listed have a SNUR under TSCA.
State Regulations
CA Right-to-Know Law:
California No Significant Risk Rule:
11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
Benzoyl Peroxide CAS #94-36-0
NONE
MA Right-to-Know Law: Titanium Dioxide CAS #13463-67-7, Benzoyl Peroxide CAS #94-36-0
NJ Right-to-Know Law: Titanium Dioxide CAS #13463-67-7, Benzoyl Peroxide CAS #94-36-0
PA Right-to-Know Law: Titanium Dioxide CAS #13463-67-7, Benzoyl Peroxide CAS #94-36-0
FL Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0
MN Right-to-Know Law: Titanium Dioxide CAS #13463-67-7, Benzoyl Peroxide CAS #94-36-0
International Regulations
CDSL: Canadian Inventory
(on Canadian Transitional List)
Polymethyl methacrylate CAS# 9011-14-7 is on the DSL List. WHMIS = n/da
Polyethylmethacrylate CAS# 9003-42-3 is on the DSL List. WHMIS = n/da
Titanium Dioxide CAS #13463-67-7, WHMIS = Not controlled.
Benzoyl Peroxide CAS #94-36-0 is on the DSL list. WHMIS = C, D2B, B4
EINECS: European Inventory: Polymer Natural:
• HAZARD SYMBOLS: Xi: Irritant
• RISK PHRASES: R36/37/38: Irritating to eyes, respiratory system and skin
• SAFETY PHRASES: S18: Handle and open container with care, S22: do not
breath dust,
S24/25: avoid contact with skin and eyes, S38: in case of
insufficient ventilation, wear suitable respiratory equipment.
Section 16 - Other Information
Hazard Rating System (Pictograms)
NFPA: HMIS:
1 1 1
* - Respiratory protection may be necessary depending on conditions of use. Refer to Section 8 of this MSDS for respiratory
protection guidelines.
OSHA PEL for nuisance dust: 15 mg/m3 (total dust) 5 mg/m3 (respirable dust)
ACGIH PEL for nuisance dust: 10 mg/m3
Revised Sections since Last Version: 1/28/05 Section 2 % changed from <,> to range, headers changed, format update
Revised Sections since Last Version: 7/18/06 Section 2 and 15 updated.
The information presented herein was obtained from sources considered to be reliable. However, this information is
provided without any warranty,
expressed or implied, regarding its correctness or suitability for consumers intended use and/or application. For this and
other reasons, we assume no
responsibility and expressly disclaim liability for loss, damage or expense arising out of any way connected with the
handling, storage, use or
disposal of the product. This MSDS was prepared expressly for this product. Use the materials only as directed. If the
product is used as a
component of another product, the information contained within the MSDS may not be applicable. If one could have
any concerns with or problems
understanding this MSDS form, please direct all questions to INFOTRAC, Chemical Emergency Resources System at
1(800) 535-5053.
1
Flammability
Reactivity Health
D

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