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SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.2. Relevant identified uses of the substance or mixture and uses advised against
HARDENER FOR TWO COMPONENT Primer. and Crack and hole filler
1.3. Details of the supplier of the safety data sheet
COO-VARLockwood StreetHullHU2 0HN+44 (0) 1482 328053(T)+44 (0) 1482 219266(F)email@example.com
Technical Department - 08.30 - 16.30 hrs Mon - Thurs, 08.30 - 15.00 hrs Fri as above
2.1. Classification of the substance or mixture
Physical and Chemical Hazards Org. Perox. C - H242Human health
Label In Accordance With (EC) No. 1272/2008
May cause an allergic skin reaction.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store at temperatures not exceeding 50 °C/122 °F. Keep cool.
Dispose of contents/container to special waste collection point
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
General informationConsult a physician for specific advice.
InhalationMove into fresh air and keep at rest. Provide fresh air, warmth and rest, preferably in a comfortable upright sitting position. Consult a physician for specific advice.
IngestionImmediately rinse mouth and provide fresh air. DO NOT INDUCE VOMITING! Get medical attention immediately!Skin contactRemove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation persists after washing. Wash contaminated clothing before reuse.
Eye contactImmediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
Extinguishing mediaExtinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Do not use water as an extinguisher. DO NOT USE: Halon. Small fires: Use: Carbon dioxide or dry powder.
5.2. Special hazards arising from the substance or mixture
Unusual Fire & Explosion HazardsOXIDISING! May explode when heated or when exposed to flames or sparks.
Specific hazardsFire or high temperatures create: Toxic gases/vapours/fumes of: Carbon dioxide (CO2). Benzoic acid. Benzene, Diphenyl 2-ethylhexyl phosphate, Phenyl benzoate,
Special Fire Fighting ProceduresBe aware of risk of fire re-starting, and risk of explosion. Decomposition under effect of heating. If involved in fire will support combustion. Avoid breathing fire vapours. Water spray should be used to cool containers.
Protective equipment for fire-figthersSelf contained breathing apparatus and full protective clothing must be worn in case of fire.
6.1. Personal precautions, protective equipment and emergency procedures
Ensure suitable personal protection (including respiratory protection) during removal of spillages in a confined area. Avoid inhalation of dust. Avoid contact with skin and eyes.
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Dampen spillage with water. Shovel into dry containers. Cover and move the containers. Flush the area with water. Avoid dust formation. Do not close container tightly. Risk of excess pressure build-up.
Avoid spilling, skin and eye contact. Mechanical ventilation or local exhaust ventilation is required. Do not eat, drink or smoke when using the product. Avoid inhalation of dust. Use explosion proof electric equipment. Eliminate all sources of ignition.
7.2. Conditions for safe storage, including any incompatibilities
Keep containers tightly closed. Store in closed original container at temperatures between 5°C and 25°C. Do not store near heat sources or expose to high temperatures. Store isolated from reducing agents. Store away from: Acids. Alkalis. heavy metal compounds(e.g. accelerators, driers, metal soaps.) Do not allow to dry out. Confinement must be avoided.
Storage ClassFlammable liquid storage. The storage and use of this product is subject to the Dangerous Substances and Explosive Atmospheres Regulations (DSEAR). The requirements are given in the HSE Approved Code of Practice and Guidance, Storage od Danderous Substances: DSEAR. Up to 50 litres of liquids with a flashpoint below 32C may be kept in a workroom provided they are kept in closed containers in a marked, fire-resisting cupboard or bin. Larger quantities must be kept in a separate, marked storeroom conforming to the structural requirements contained in the HSE guidance note Storage of Flammable Liquids in Containers.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredient CommentsWEL = Workplace Exposure Limits OES = Occupational Exposure Standard.
Engineering measuresProvide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of dust. Provide explosion proof ventilation for high concentrations.
Respiratory equipmentWear respirator if there is dust formation. Use respiratory equipment with particle filter, type P1.
Hand protectionUse suitable protective gloves if risk of skin contact. Neoprene gloves are recommended.
Eye protectionUse approved safety goggles or face shield.
Other ProtectionWear appropriate clothing to prevent any possibility of skin contact. Launder clothes before reuse.
Hygiene measuresNo specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Initial boiling point and boiling range Do not heatRelative density
SADT- (Self accelerating decomposition temperature) is the lowest temperature at which self accelerating decomposition may occur with a substance in the packaging used for transport. A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by thermal decomposion at and above the following temperature: 55C. Contact with incompatible substances can cause decomposition at or below the SADT.
Avoid temperatures above 25 C. Confinement must be avoided. DO NOT ALLOW TO DRY OUT. Explosive when dry.
Materials To AvoidAvoid contact with rust, iron copper. Contact with incompatible materials such as acids, alkalies, heavy metals and reducing agents will result in hazardous decomposition.
11.1. Information on toxicological effects
>5000 (Dibenzoyl peroxide) mg/kg (oral rat)
>24.3; - (dibenzoyl peroxide) mg/l/4h (inh-rat)
Toxicological informationAmes test: Not mutagenic.
Skin contactSkin irritation is not anticipated when used normally. May cause sensitisation by skin contact.
Eye contactIrritating to eyes.
2.0 (poecilla reticulata.) - Dibenzoyl peroxide
DegradabilityThe product is easily biodegradable.
General informationWhen handling waste, consideration should be made to the safety precautions applying to handling of the product. Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.
Dispose of waste and residues in accordance with local authority requirements. Incinerate in suitable combustion chamber.
Waste ClassIdeally this component should be mixed with the appropriate resin base and allowed to react fully producing a solid non hazardous waste.
This product is packed in accordance with the Limited Quantity Provisions of CDGCPL2, ADR and IMDG.
Organic peroxide type d, solid; (Dibenzoyl peroxide)
Environmentally Hazardous Substance/Marine PollutantNo.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory ReferencesThe Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.
Statutory InstrumentsThe Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health.
Approved Code Of PracticeSafety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138]Guidance NotesWorkplace Exposure Limits EH40. CHIP for everyone HSG(108).
EU LegislationRegulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.
National RegulationsThe Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.
No chemical safety assessment has been carried out.
General informationOnly trained personnel should use this material.
Revision CommentsIssued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010 Correction to classificationIssued By
Extreme risk of explosion by shock, friction, fire or other sources of ignition.
May cause sensitisation by skin contact.
Heating may cause a fire or explosion.
May cause an allergic skin reaction.
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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