Microsoft word - bird brand complete wood preserver 2012.doc
MATERIAL DATA SHEET Revised 1st Nov 2012 BIRD BRAND COMPLETE WOOD PRESERVER SECTION 1: IDENTIFICATION OF SUBSTANCE/PREPARATION & COMPANY Product/Material: SOLVENT BASED WOOD PRESERVER Supplier: Address: Telephone:
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS CLASSIFICATION
Hydrodesulfurized Heavy Pigment colourants
The full text for all R-Phrases are displayed in section 16. SECTION 3: HAZARDS IDENTIFICATION
Flammable. Repeated exposure may cause skin dryness or cracking. Harmful: may cause lung damage if swallowed. Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. CLASSIFICATION
SECTION 4: FIRST AID MEASURES General Information:
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.
Inhalation:
Move the exposed person to fresh air at once. Get medical attention. Provide rest, warmth and fresh air. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen.
Ingestion:
DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! If vomiting occurs, keep head low so that stomach content doesn’t get into the lungs. Drink plenty of water. Get medical attention immediately! Provide rest, warmth and fresh air.
Skin Contact:
Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after washing.
Eye Contact:
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. Get prompt medical attention.
Product: Bird Brand Complete Wood Preserver
SECTION 5 : FIRE FIGHTING MEASURES
Extinguishing Media:
Fire can be extinguished using: Foam. Dry chemicals, sand, dolomite etc. Water spray, fog or mist. DO NOT use direct water jet as this will scatter and spread the fire.
Specific Fire Fighting Procedures:
Avoid breathing fire vapours. Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control.
Unusual Fire & Explosion Hazards:
Vapours are heavier than air and may spread near ground to sources of ignition. May travel considerable distance to source of ignition and flash back. May form explosive mixture with air particularly with in empty un-cleaned receptacles.
Protective measures in fire:
Wear self-contained breathing apparatus and full protective clothing.
SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions:
Ventilate area. Avoid breathing vapours. Remove all sources of ignition
Wear suitable protective clothing as specified under section 8 of this
Safety data sheet – Exposure Controls and Personal Protection.
Environmental Precautions: Do not allow spilled material to enter drains or water courses. Spill Clean Up Methods:
Wear necessary protective equipment. Absorb in vermiculite, dry sand
or earth and place into containers. Dispose of in accordance with Local
Authority Regulations via a licensed waste carrier. Do not contaminate
SECTION 7 : HANDLING AND STORAGE Usage Precautions:
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ensure adequate ventilation during spraying or wear appropriate respirator during such operations. Do not use on internal timbers.
Storage Precautions:
Store in tightly closed original container in a cool, dry well-ventilated place. Keep in original container.
Storage Class:
SECTION 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION Name LT-mg/m3 ST-mg/m3
Naptha (Petroleum), WEL 800 mg/m3 Hydrodesulfrized Protective Equipment PROCESS CONDITIONS FOR OUTDOOR USE ONLY. Ingredient Comments
WEL= Workplace Exposure Limits. Engineering Measures:
Provide adequate general and local exhaust ventilation.
Respiratory Equipment:
No specific recommendation made, but respiratory protection must be
used if the general level exceeds the Recommended Occupational
Product: Bird Brand Complete Wood Preserver
Hand Protection:
Use protective gloves made of: Nitrile or Neoprene.
Eye Protection:
Other Protection:
Wear appropriate clothing to prevent any possibility of liquid contact
and repeated or prolonged vapour contact.
Hygiene Measures:
DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift
and before eating, smoking and using the toilet. Promptly remove any
clothing that becomes contaminated. Wash promptly with soap and
water if skin becomes contaminated. Use appropriate skin cream to
prevent drying of the skin. When using do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES. Appearance: Solubility Description: Boiling Point(oC) Flash Point: Vapour density: Vapour pressure: Viscosity: Auto Ignition: Flammability limit-upper% Flammability limit-lower% Physical Data Comments:
Information given concerns the major ingredient.
SECTION 10 : STABILITY AND REACTIVITY
Stability:
Stable under normal temperature conditions.
Conditions to avoid:
Avoid contact with acids and oxidising substances.
Hazardous decomposition Products:
Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO)
SECTION 11: TOXICOLOGICAL INFORMATION Inhalation:
Exposure to organic solvent vapours in excess of the stated
occupational exposure limit may result in adverse effects such as
Irritation of the mucous membrane and the respiratory system and
adverse effects on kidney, liver and central nervous system.
symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and in extreme cases, loss of conciousness.
Skin Contact:
Repeated or prolonged contact with organic solvents may cause
removal of natural fats from the skin, resulting in non-allergic contact
dermatitis and absorption through the skin.
Eye Contact:
Spray and vapour in the eyes may cause irritation and smarting.
Ingestion:
Liquid irritates mucous membranes and may cause abdominal pain if
swallowed. Significant absorption may cause sleepiness, intoxication and pulmonary oedema.
Health Warnings:
The product causes irritation of mucous membranes and may cause
Product: Bird Brand Complete Wood Preserver
Target Organs:
SECTION 12 : ECOLOGICAL INFORMATION Eco-toxicity:
The product contains a substance which is very toxic to aquatic
organisms. Do not allow to contaminate drains, sewers or water
courses. Harmful to animals and plants in wet state but once dry
(24 hours) the product is safe. Splashes on leaves of plants will
cause burns but long term systemic damage is unlikely.
Mobility:
Water: Insoluble: the product spreads over the surface of the water and
will slowly evaporate. Soil: the product has only slight mobility in the
Bioaccumulation:
Likely to bio-accumulate but with short retention time in the order of a
Degradability:
Readily biodegradable. The biodegradability after 28 days was found to
Be 314% when expressed as a ratio of the biochemical oxygen demand
(BOD) to the Chemical Oxygen Demand (COD)
Acute Fish Toxicity:
Dangerous to fish and other aquatic organisms.
SECTION 13: DISPOSAL CONSIDERATIONS
Disposal Methods:
Dispose of waste and residues in accordance with local authority
Waste Class:
This material should be considered as ‘Special Waste’ and disposal
should conform with the relevant regulations.
SECTION 14 : TRANSPORT INFORMATION UK Road Class: Proper Shipping Name: Wood Preservatives UN No.Road: Uk Road Pack GR.: ADR Class No.: ADR Class: Class 3:Flammable Liquids. ADR Pack Group: Hazard No.(ADR) ADR Label No: Hazchem code: Rid Class No: Rid Pack Group: UN No. Sea: IMDG Class: See Guide Marine Pollutant: Un No.Air: Air Class: Air Pack GR: IMDG Page No: IMDG Pack GR: SECTION 15 : REGULATORY INFORMATION Labelling: Harmful/Dangerous for the Environment Contains: Naptha (Petroleum) Hydrodesulfurized Heavy
Risk Phrases:
Toxic to aquatic organisms, may cause long term
Product: Bird Brand Complete Wood Preserver
adverse effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or
Safety Phrases:
Keep away from food, drink and animal feeding stuffs.
Do not empty into drains, dispose of this material
and its container at hazardous or special waste
If swallowed, seek medical advice immediately
Avoid release to the environment. Refer to special
Contains propiconazole/Permethrin. May produce an allergic reaction.
Statutory Instruments:
Chemicals (Hazard Information and Packaging) Regulations
Approved code of practise:
Classification and Labelling of Substances and Preparations
Guidance Notes:
Occupational Exposure Limits EH40. Introduction to Local Exhaust
Ventilation HS (G)37. CHIP for everyone HSG (108)
EU Directives:
System of specific information relating to Dangerous Preparations.
SECTION 16 : OTHER HEALTH AND SAFETY INFORMATION
Information Sources:
Dangerous Properties of Industrial Materials Report, N.Sax et.al.
Risk Phrases in full: NC Not Classified Flammable Harmful if swallowed May cause sensitisation by skin contact Very toxic to aquatic organisms, may cause long-term adverse effects in the Aquatic environment. Toxic to aquatic organisms, may cause long term adverse effects in the aquatic Environment. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. References should be made to the Health & Safety at Work Act. Disclaimer: If this product is re-distributed and re-formulated for sale, details of its hazards and recommended methods for safe handling must be passed to customers. Customers are urged to ensure that the product is entirely suitable for their own purpose. It is the customer’s responsibility to ensure that a suitable and sufficient assessment of the risks created by a work activity using this product is undertaken before this product is used. Note: The information contained in this Safety Data Sheet does not constitute the users own assessment of workplace risk as required by other Health & Safety Legislation (e.g. the Health and Safety at Work Act,1974;the control of Substances Hazardous to Health Regulations,1988). The data given here is based on current knowledge and experience. The purpose of this data sheet is to describe the products in terms of their safety requirements. The data does not signify any warranty with regard to the product's properties. REVISED 1st November 2012
Product: Bird Brand Complete Wood Preserver
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